13C n.m.r. investigation on the first and second nitrogen protonation in the diazanaphthalenes

Peter van de Weijer, Dirk M.W. van den Ham, Douwe van der Meer

Research output: Contribution to journalArticleAcademic

15 Citations (Scopus)

Abstract

The 13C chemical shifts of the diazanaphthalenes have been recorded as a function of the pH value, providing classical titration curves. From these curves the pK1 and pK2 values have been determined taking into account the activity coefficients. The changes in 13C chemical shift under the influence of nitrogen protonation (Δδ) can be described by two protonation parameter sets.
Original languageUndefined
Pages (from-to)281-284
JournalOrganic Magnetic Resonance
Volume9
Issue number5
DOIs
Publication statusPublished - 1977
Externally publishedYes

Keywords

  • IR-70731

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