13C n.m.r. investigation on the nitrogen methylation of some azabenzenes

Peter van de Weijer, Chandra Mohan

Research output: Contribution to journalArticleAcademic

13 Citations (Scopus)

Abstract

The 1H and 13C n.m.r. spectra of N-methylated pyridine, pyridazine, pyrimidine and pyrazine and N,N-dimethylated pyrimidine and pyrazine have been recorded and analysed. The change in the 13C chemical shifts under the influence of N-methylation (Δδ) in the diazabenzenes could be predicted by the Δδ values of pyridine. A comparison of the Δδ values of N-methylation with those of N-protonation showed that both reactions have a similar effect.
Original languageUndefined
Pages (from-to)53-55
JournalOrganic Magnetic Resonance
Volume9
Issue number1
DOIs
Publication statusPublished - 1977
Externally publishedYes

Keywords

  • IR-70730

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