15,17-Di-2-propenylcalix[4]arene-25,26,27,28-tetrol: self-complexation and C-H...O interactions

Sybolt Harkema; Jan-Dirk van Loon; Jan-Dirk van Loon; Willem Verboom; David Reinhoudt

doi:10.1107/S0108270197010937

15,17-Di-2-propenylcalix[4]arene-25,26,27,28-tetrol: self-complexation and C-H...O interactions

Sybolt Harkema, Jan-Dirk van Loon, Jan-Dirk van Loon, Willem Verboom, David Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The crystal structure of 15,17-di-2-propenylcalix[4]arene-25,26,27,28-tetrol [systematic name: 15,17-di-2-propenylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25), 3,5,7(26),9,11,13 (27),15,17,19 (28),21,23-dodecaene-25,26,27,28-tetrol], C34H32O4, was determined. The calix[4]arene molecule shows a cone conformation, stabilized by a ring-like hydrogen-bond pattern of the four hydroxyl H atoms. In the crystal structure, complexation of one of the propenyl side chains in the cavity of another calixarene molecule is found. The other side chain shows C-HO interactions with a neighbouring calixarene molecule.

Original language	Undefined
Pages (from-to)	269-271
Number of pages	3
Journal	Acta crystallographica. Section C: Crystal structure communications
Volume	54
Issue number	C54
DOIs	https://doi.org/10.1107/S0108270197010937
Publication status	Published - 1998

Keywords

METIS-129092
IR-24292

Access to Document

10.1107/S0108270197010937

Cite this

@article{8ffd0565661e4d3086eaab7b6a20ecdc,

title = "15,17-Di-2-propenylcalix[4]arene-25,26,27,28-tetrol: self-complexation and C-H...O interactions",

abstract = "The crystal structure of 15,17-di-2-propenylcalix[4]arene-25,26,27,28-tetrol [systematic name: 15,17-di-2-propenylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25), 3,5,7(26),9,11,13 (27),15,17,19 (28),21,23-dodecaene-25,26,27,28-tetrol], C34H32O4, was determined. The calix[4]arene molecule shows a cone conformation, stabilized by a ring-like hydrogen-bond pattern of the four hydroxyl H atoms. In the crystal structure, complexation of one of the propenyl side chains in the cavity of another calixarene molecule is found. The other side chain shows C-HO interactions with a neighbouring calixarene molecule.",

keywords = "METIS-129092, IR-24292",

author = "Sybolt Harkema and {van Loon}, Jan-Dirk and {van Loon}, Jan-Dirk and Willem Verboom and David Reinhoudt",

year = "1998",

doi = "10.1107/S0108270197010937",

language = "Undefined",

volume = "54",

pages = "269--271",

journal = "Acta crystallographica. Section C: Crystal structure communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "C54",

}

TY - JOUR

T1 - 15,17-Di-2-propenylcalix[4]arene-25,26,27,28-tetrol: self-complexation and C-H...O interactions

AU - Harkema, Sybolt

AU - van Loon, Jan-Dirk

AU - Verboom, Willem

AU - Reinhoudt, David

PY - 1998

Y1 - 1998

N2 - The crystal structure of 15,17-di-2-propenylcalix[4]arene-25,26,27,28-tetrol [systematic name: 15,17-di-2-propenylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25), 3,5,7(26),9,11,13 (27),15,17,19 (28),21,23-dodecaene-25,26,27,28-tetrol], C34H32O4, was determined. The calix[4]arene molecule shows a cone conformation, stabilized by a ring-like hydrogen-bond pattern of the four hydroxyl H atoms. In the crystal structure, complexation of one of the propenyl side chains in the cavity of another calixarene molecule is found. The other side chain shows C-HO interactions with a neighbouring calixarene molecule.

AB - The crystal structure of 15,17-di-2-propenylcalix[4]arene-25,26,27,28-tetrol [systematic name: 15,17-di-2-propenylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25), 3,5,7(26),9,11,13 (27),15,17,19 (28),21,23-dodecaene-25,26,27,28-tetrol], C34H32O4, was determined. The calix[4]arene molecule shows a cone conformation, stabilized by a ring-like hydrogen-bond pattern of the four hydroxyl H atoms. In the crystal structure, complexation of one of the propenyl side chains in the cavity of another calixarene molecule is found. The other side chain shows C-HO interactions with a neighbouring calixarene molecule.

KW - METIS-129092

KW - IR-24292

U2 - 10.1107/S0108270197010937

DO - 10.1107/S0108270197010937

M3 - Article

SN - 0108-2701

VL - 54

SP - 269

EP - 271

JO - Acta crystallographica. Section C: Crystal structure communications

JF - Acta crystallographica. Section C: Crystal structure communications

IS - C54

ER -