IR study on the reaction path of methanol decomposition over basic zeolites

M. Rep, J.G. van Ommen, L. Lefferts, J.A. Lercher

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

2 Citations (Scopus)

Abstract

This chapter presents infrared (IR) study on the reaction path of methanol decomposition over basic zeolites. Based on an infrared study of the adsorption and reaction of methanol and dimethyl ether over alkali metal cation exchanged zeolites, a reaction mechanism is proposed for the decomposition of methanol over alkali cation exchanged zeolites.Formaldehyde adsorption is performed on these molecular sieves and attempts are made to correlate its adsorption structure with the surface reactivity.
Original languageEnglish
Title of host publicationZeolites and mesoporous materials at the dawn of the 21st century
Subtitle of host publicationproceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001
EditorsA. Galarneau, F. Fajula, F. Di Renzo, J. Vedrine
Place of PublicationAmsterdam
PublisherElsevier
Pages316-323
Number of pages8
ISBN (Print)0444502386
DOIs
Publication statusPublished - 2001
Event13th International Zeolite Conference, IZC 2001: Zeolites and Mesoporous Materials at the Dawn of the 21st Century - Montpellier, France
Duration: 8 Jun 200113 Jun 2001
Conference number: 13

Publication series

NameStudies in surface science and catalysis
PublisherElsevier
Volume135
ISSN (Print)0167-2991

Conference

Conference13th International Zeolite Conference, IZC 2001
Abbreviated titleIZC
CountryFrance
CityMontpellier
Period8/06/0113/06/01

Fingerprint

Zeolites
Methanol
Infrared radiation
Decomposition
Adsorption
Cations
Alkali Metals
Molecular sieves
Alkalies
Formaldehyde

Cite this

Rep, M., van Ommen, J. G., Lefferts, L., & Lercher, J. A. (2001). IR study on the reaction path of methanol decomposition over basic zeolites. In A. Galarneau, F. Fajula, F. Di Renzo, & J. Vedrine (Eds.), Zeolites and mesoporous materials at the dawn of the 21st century: proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001 (pp. 316-323). (Studies in surface science and catalysis; Vol. 135). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(01)81715-8
Rep, M. ; van Ommen, J.G. ; Lefferts, L. ; Lercher, J.A. / IR study on the reaction path of methanol decomposition over basic zeolites. Zeolites and mesoporous materials at the dawn of the 21st century: proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001. editor / A. Galarneau ; F. Fajula ; F. Di Renzo ; J. Vedrine. Amsterdam : Elsevier, 2001. pp. 316-323 (Studies in surface science and catalysis).
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title = "IR study on the reaction path of methanol decomposition over basic zeolites",
abstract = "This chapter presents infrared (IR) study on the reaction path of methanol decomposition over basic zeolites. Based on an infrared study of the adsorption and reaction of methanol and dimethyl ether over alkali metal cation exchanged zeolites, a reaction mechanism is proposed for the decomposition of methanol over alkali cation exchanged zeolites.Formaldehyde adsorption is performed on these molecular sieves and attempts are made to correlate its adsorption structure with the surface reactivity.",
author = "M. Rep and {van Ommen}, J.G. and L. Lefferts and J.A. Lercher",
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language = "English",
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series = "Studies in surface science and catalysis",
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Rep, M, van Ommen, JG, Lefferts, L & Lercher, JA 2001, IR study on the reaction path of methanol decomposition over basic zeolites. in A Galarneau, F Fajula, F Di Renzo & J Vedrine (eds), Zeolites and mesoporous materials at the dawn of the 21st century: proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001. Studies in surface science and catalysis, vol. 135, Elsevier, Amsterdam, pp. 316-323, 13th International Zeolite Conference, IZC 2001, Montpellier, France, 8/06/01. https://doi.org/10.1016/S0167-2991(01)81715-8

IR study on the reaction path of methanol decomposition over basic zeolites. / Rep, M.; van Ommen, J.G.; Lefferts, L.; Lercher, J.A.

Zeolites and mesoporous materials at the dawn of the 21st century: proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001. ed. / A. Galarneau; F. Fajula; F. Di Renzo; J. Vedrine. Amsterdam : Elsevier, 2001. p. 316-323 (Studies in surface science and catalysis; Vol. 135).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

TY - GEN

T1 - IR study on the reaction path of methanol decomposition over basic zeolites

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AU - van Ommen, J.G.

AU - Lefferts, L.

AU - Lercher, J.A.

PY - 2001

Y1 - 2001

N2 - This chapter presents infrared (IR) study on the reaction path of methanol decomposition over basic zeolites. Based on an infrared study of the adsorption and reaction of methanol and dimethyl ether over alkali metal cation exchanged zeolites, a reaction mechanism is proposed for the decomposition of methanol over alkali cation exchanged zeolites.Formaldehyde adsorption is performed on these molecular sieves and attempts are made to correlate its adsorption structure with the surface reactivity.

AB - This chapter presents infrared (IR) study on the reaction path of methanol decomposition over basic zeolites. Based on an infrared study of the adsorption and reaction of methanol and dimethyl ether over alkali metal cation exchanged zeolites, a reaction mechanism is proposed for the decomposition of methanol over alkali cation exchanged zeolites.Formaldehyde adsorption is performed on these molecular sieves and attempts are made to correlate its adsorption structure with the surface reactivity.

U2 - 10.1016/S0167-2991(01)81715-8

DO - 10.1016/S0167-2991(01)81715-8

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SN - 0444502386

T3 - Studies in surface science and catalysis

SP - 316

EP - 323

BT - Zeolites and mesoporous materials at the dawn of the 21st century

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CY - Amsterdam

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Rep M, van Ommen JG, Lefferts L, Lercher JA. IR study on the reaction path of methanol decomposition over basic zeolites. In Galarneau A, Fajula F, Di Renzo F, Vedrine J, editors, Zeolites and mesoporous materials at the dawn of the 21st century: proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001. Amsterdam: Elsevier. 2001. p. 316-323. (Studies in surface science and catalysis). https://doi.org/10.1016/S0167-2991(01)81715-8