9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

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Abstract

9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.
Original languageUndefined
Pages (from-to)4413-4416
JournalTetrahedron letters
Volume42
Issue number26
DOIs
Publication statusPublished - 2001

Keywords

  • METIS-202830
  • IR-36701

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