9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

Huiqi Zhang; Willem Verboom; David Reinhoudt

doi:10.1016/S0040-4039(01)00738-9

9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

Huiqi Zhang, Willem Verboom, David Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

27 Citations (Scopus)

5 Downloads (Pure)

Abstract

9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.

Original language	Undefined
Pages (from-to)	4413-4416
Journal	Tetrahedron letters
Volume	42
Issue number	26
DOIs	https://doi.org/10.1016/S0040-4039(01)00738-9
Publication status	Published - 2001

Keywords

METIS-202830
IR-36701

Access to Document

10.1016/S0040-4039(01)00738-9

Cite this

@article{b1631871a61f49ca87298628faf0ec35,

title = "9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs",

abstract = "9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.",

keywords = "METIS-202830, IR-36701",

author = "Huiqi Zhang and Willem Verboom and David Reinhoudt",

note = "643 ",

year = "2001",

doi = "10.1016/S0040-4039(01)00738-9",

language = "Undefined",

volume = "42",

pages = "4413--4416",

journal = "Tetrahedron letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "26",

}

TY - JOUR

T1 - 9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

AU - Zhang, Huiqi

AU - Verboom, Willem

AU - Reinhoudt, David

N1 - 643

PY - 2001

Y1 - 2001

N2 - 9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.

AB - 9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.

KW - METIS-202830

KW - IR-36701

U2 - 10.1016/S0040-4039(01)00738-9

DO - 10.1016/S0040-4039(01)00738-9

M3 - Article

SN - 0040-4039

VL - 42

SP - 4413

EP - 4416

JO - Tetrahedron letters

JF - Tetrahedron letters

IS - 26

ER -