A Brush/Gel Metal-Nanoparticle Hybrid Film as an Efficient Supported Catalyst in Glass Microreactors

Francesca Costantini; Edmondo M. Benetti; Roald M. Tiggelaar; Han J.G.E. Gardeniers; David N. Reinhoudt; Jurriaan Huskens; G. Julius Vancso; Willem Verboom

doi:10.1002/chem.201000948

A Brush/Gel Metal-Nanoparticle Hybrid Film as an Efficient Supported Catalyst in Glass Microreactors

Francesca Costantini, Edmondo M. Benetti, Roald M. Tiggelaar, Han J.G.E. Gardeniers, David N. Reinhoudt, Jurriaan Huskens, G. Julius Vancso, Willem Verboom

Research output: Contribution to journal › Article › Academic › peer-review

77 Citations (Scopus)

19 Downloads (Pure)

Abstract

A polymer-brush-based material was applied for the formation and in situ immobilization of silver and palladium nanoparticles, as a catalytic coating on the inner wall of glass microreactors. The brush film was grown directly on the microchannel interior by means of atom-transfer radical polymerization (ATRP), which allows control over the polymer film thickness and therefore permits the tuning of the number of nanoparticles formed on the channel walls. The wide applicability of the catalytic devices is demonstrated for the reduction of 4-nitrophenol and for the Heck reaction

Original language	English
Pages (from-to)	12406-12411
Number of pages	6
Journal	Chemistry : a European journal
Volume	16
Issue number	41
DOIs	https://doi.org/10.1002/chem.201000948
Publication status	Published - 2010

Keywords

2024 OA procedure

Access to Document

10.1002/chem.201000948

ArticleFinal published version, 373 KBLicence: Taverne

Cite this

@article{827f97bc6c614b879fc908743a79b215,

title = "A Brush/Gel Metal-Nanoparticle Hybrid Film as an Efficient Supported Catalyst in Glass Microreactors",

abstract = "A polymer-brush-based material was applied for the formation and in situ immobilization of silver and palladium nanoparticles, as a catalytic coating on the inner wall of glass microreactors. The brush film was grown directly on the microchannel interior by means of atom-transfer radical polymerization (ATRP), which allows control over the polymer film thickness and therefore permits the tuning of the number of nanoparticles formed on the channel walls. The wide applicability of the catalytic devices is demonstrated for the reduction of 4-nitrophenol and for the Heck reaction",

keywords = "2024 OA procedure",

author = "Francesca Costantini and Benetti, {Edmondo M.} and Tiggelaar, {Roald M.} and Gardeniers, {Han J.G.E.} and Reinhoudt, {David N.} and Jurriaan Huskens and Vancso, {G. Julius} and Willem Verboom",

year = "2010",

doi = "10.1002/chem.201000948",

language = "English",

volume = "16",

pages = "12406--12411",

journal = "Chemistry : a European journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "41",

}

TY - JOUR

T1 - A Brush/Gel Metal-Nanoparticle Hybrid Film as an Efficient Supported Catalyst in Glass Microreactors

AU - Costantini, Francesca

AU - Benetti, Edmondo M.

AU - Tiggelaar, Roald M.

AU - Gardeniers, Han J.G.E.

AU - Reinhoudt, David N.

AU - Huskens, Jurriaan

AU - Vancso, G. Julius

AU - Verboom, Willem

PY - 2010

Y1 - 2010

N2 - A polymer-brush-based material was applied for the formation and in situ immobilization of silver and palladium nanoparticles, as a catalytic coating on the inner wall of glass microreactors. The brush film was grown directly on the microchannel interior by means of atom-transfer radical polymerization (ATRP), which allows control over the polymer film thickness and therefore permits the tuning of the number of nanoparticles formed on the channel walls. The wide applicability of the catalytic devices is demonstrated for the reduction of 4-nitrophenol and for the Heck reaction

AB - A polymer-brush-based material was applied for the formation and in situ immobilization of silver and palladium nanoparticles, as a catalytic coating on the inner wall of glass microreactors. The brush film was grown directly on the microchannel interior by means of atom-transfer radical polymerization (ATRP), which allows control over the polymer film thickness and therefore permits the tuning of the number of nanoparticles formed on the channel walls. The wide applicability of the catalytic devices is demonstrated for the reduction of 4-nitrophenol and for the Heck reaction

KW - 2024 OA procedure

U2 - 10.1002/chem.201000948

DO - 10.1002/chem.201000948

M3 - Article

SN - 0947-6539

VL - 16

SP - 12406

EP - 12411

JO - Chemistry : a European journal

JF - Chemistry : a European journal

IS - 41

ER -

A Brush/Gel Metal-Nanoparticle Hybrid Film as an Efficient Supported Catalyst in Glass Microreactors

Abstract

Keywords

Access to Document

Fingerprint

Cite this