A comparative study of techniques used for porous membrane characterization: pore characterization

K.J. Kim, A.G. Fane*, R. Ben Aim, M.G. Liu, G. Jonsson, I.C. Tessaro, A.P. Broek, D. Bargeman

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

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A range of commerical UF membranes have been characterized by thermoporometry, biliquid permporometry and molecular weight cut-off experiments. A comparison of results from these three independent techniques for the same types of membrane shows an indication of the strength and weakness of the methods. MWCO values determined from actual rejection values using PEG and dextran were significantly lower than the manufacturer supplied data. The data obtained using the biliquid permporometry and solute rejection tests produced contrasting results for Amicon polysulfone (PM30) and regenerated cellulose (YM30) membranes. While MWCO determination resulted in sharper cut-off curves, the biliquid permporometry offered a broader size distribution with the PM30 and vice versa with the YM30. The pore sizes obtained by thermoporometry were significantly larger than those by the biliquid permporometry. The biliquid permporometry and thermoporometry give significantly higher values than the MWCO method. The closest comparison is obtained between the EM values and the MWCO method. This suggests that the controlling pore dimension for separation is the surface skin dimension.
Original languageEnglish
Pages (from-to)35-46
Number of pages12
JournalJournal of membrane science
Issue number1-2
Publication statusPublished - 1994


  • Biliquid
  • Molecular weight cut-off
  • Thermoporometry
  • Pore characterization
  • Permporometry
  • Ultra filtration
  • Microporous and porous membranes


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