A generalized network model for polymeric liquids

A kinetic model was developed for relating the molecular structure and the rheological behaviour of polymer-like materials in which bonds are being created and broken. In particular, the stress contribution of molecules that are not a part of the network was taken account of. In two limiting cases the model introduced here is identical to the transient-network model and the bead-spring model, respectively. Model predictions were interpreted and compared with measurements on an L.D.-polyethylene melt, available from literature, and an S.I.S.-blockcopolymer solution. In both cases information was obtained about the network and the kinetic processes occurring in a state of rest and during steady-shear flow, assuming the model to be valid.