A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers

W. Osikowicz; A.W. Denier van der Gon; X. Crispin; M.P. de Jong; R. Friedlein; L. Groenendaal; M. Fahlman; D. Beljonne; R. Lazzaroni; W.R. Salaneck

doi:10.1063/1.1617273

A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers

W. Osikowicz^*, A.W. Denier van der Gon, X. Crispin, M.P. de Jong, R. Friedlein, L. Groenendaal, M. Fahlman, D. Beljonne, R. Lazzaroni, W.R. Salaneck

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

11 Citations (Scopus)

Abstract

The electronic structure of a series of phenyl-capped EDOT oligomers was studied using ultraviolet photoelectron spectroscopy, in combination with quantum-chemical methods. The bulk IP of the neutral PEDOT polymer was estimated to be 4.2 eV. The frontier band structue was predicted from the evolution of the spectral features in the studied series of oligomers.

Original language	English
Pages (from-to)	10415-10420
Number of pages	6
Journal	The Journal of chemical physics
Volume	119
Issue number	19
DOIs	https://doi.org/10.1063/1.1617273
Publication status	Published - 15 Nov 2003
Externally published	Yes

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10.1063/1.1617273

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Osikowicz, W., Denier van der Gon, A. W., Crispin, X., de Jong, M. P., Friedlein, R., Groenendaal, L., Fahlman, M., Beljonne, D., Lazzaroni, R., & Salaneck, W. R. (2003). A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers. The Journal of chemical physics, 119(19), 10415-10420. https://doi.org/10.1063/1.1617273

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Osikowicz, W, Denier van der Gon, AW, Crispin, X, de Jong, MP, Friedlein, R, Groenendaal, L, Fahlman, M, Beljonne, D, Lazzaroni, R & Salaneck, WR 2003, 'A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers', The Journal of chemical physics, vol. 119, no. 19, pp. 10415-10420. https://doi.org/10.1063/1.1617273

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T1 - A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers

AU - Osikowicz, W.

AU - Denier van der Gon, A.W.

AU - Crispin, X.

AU - de Jong, M.P.

AU - Friedlein, R.

AU - Groenendaal, L.

AU - Fahlman, M.

AU - Beljonne, D.

AU - Lazzaroni, R.

AU - Salaneck, W.R.

PY - 2003/11/15

Y1 - 2003/11/15

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AB - The electronic structure of a series of phenyl-capped EDOT oligomers was studied using ultraviolet photoelectron spectroscopy, in combination with quantum-chemical methods. The bulk IP of the neutral PEDOT polymer was estimated to be 4.2 eV. The frontier band structue was predicted from the evolution of the spectral features in the studied series of oligomers.

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DO - 10.1063/1.1617273

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ER -

A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers

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