TY - JOUR
T1 - A method for the determination of the dissociation constants of acids with an uncalibrated glass electrode
AU - Bos, M.
AU - Lengton, W.
PY - 1975
Y1 - 1975
N2 - A method is presented for the determination of absolute pKa values of acids in solvents with a high dielectric constant by potentiometry with an uncalibrated glass electrode; in the determination, the glass electrode becomes calibrated. The method has the advantage that it is rapid and simple. Moreover, the range of pKa values that can be determined by this method is about 3 pK units greater than for the direct conductivity method.
AB - A method is presented for the determination of absolute pKa values of acids in solvents with a high dielectric constant by potentiometry with an uncalibrated glass electrode; in the determination, the glass electrode becomes calibrated. The method has the advantage that it is rapid and simple. Moreover, the range of pKa values that can be determined by this method is about 3 pK units greater than for the direct conductivity method.
KW - IR-68317
U2 - 10.1016/S0003-2670(01)81996-6
DO - 10.1016/S0003-2670(01)81996-6
M3 - Article
SN - 0003-2670
VL - 76
SP - 149
EP - 154
JO - Analytica chimica acta
JF - Analytica chimica acta
IS - 1
ER -