A method for the determination of the dissociation constants of acids with an uncalibrated glass electrode

M. Bos, W. Lengton

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A method is presented for the determination of absolute pKa values of acids in solvents with a high dielectric constant by potentiometry with an uncalibrated glass electrode; in the determination, the glass electrode becomes calibrated. The method has the advantage that it is rapid and simple. Moreover, the range of pKa values that can be determined by this method is about 3 pK units greater than for the direct conductivity method.
Original languageUndefined
Pages (from-to)149-154
JournalAnalytica chimica acta
Issue number1
Publication statusPublished - 1975


  • IR-68317

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