A molecular “screw-clamp”: Accelerating click reactions in miniemulsions

Evandro M. Alexandrino; Manfred Wagner; Adrian Fuchs; Andreas Kreyes; Clemens K. Weiss; Katharina Landfester; Frederik R. Wurm

doi:10.1039/c4cc04119d

A molecular “screw-clamp”: Accelerating click reactions in miniemulsions

Evandro M. Alexandrino, Manfred Wagner, Adrian Fuchs, Andreas Kreyes, Clemens K. Weiss, Katharina Landfester, Frederik R. Wurm^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

10 Citations (Scopus)

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Abstract

The interface as a “screw clamp”: the copper-free 1,3-dipolar azide–alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil–water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.

Original language	English
Pages (from-to)	10495-10498
Number of pages	4
Journal	Chemical communications
Volume	50
Issue number	72
DOIs	https://doi.org/10.1039/c4cc04119d
Publication status	Published - 12 Aug 2014
Externally published	Yes

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Alexandrino-2014-A-molecular-screw-clamp-acceleratinFinal published version, 1.75 MBLicence: CC BY

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