A molecular “screw-clamp”: Accelerating click reactions in miniemulsions

Evandro M. Alexandrino, Manfred Wagner, Adrian Fuchs, Andreas Kreyes, Clemens K. Weiss, Katharina Landfester, Frederik R. Wurm*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)
28 Downloads (Pure)

Abstract

The interface as a “screw clamp”: the copper-free 1,3-dipolar azide–alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil–water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.

Original languageEnglish
Pages (from-to)10495-10498
Number of pages4
JournalChemical communications
Volume50
Issue number72
DOIs
Publication statusPublished - 12 Aug 2014
Externally publishedYes

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