Abstract
A multigrid algorithm has been developed enabling more efficient solution of the cluster size distribution for N-component nucleation from the Becker-Döring equations. The theoretical derivation is valid for an arbitrary number of condensing components, making the simulation of many-component nucleating systems feasible. A steady state ternary nucleation problem is defined to demonstrate its efficiency. The results are used as a validation for existing nucleation theories. The non-steady state ternary problem provides useful insight into the initial stages of the nucleation process. We observe that for the ideal mixture the main nucleation flux bypasses the saddle point.
| Original language | English |
|---|---|
| Article number | 014114 |
| Number of pages | 8 |
| Journal | The Journal of chemical physics |
| Volume | 135 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2011 |
Keywords
- 2020 OA procedure
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