A nesting conformation of the 5′-bromo-1′,3′-xylyl-18-crown-5·tert-butylammonium hexafluorophosphate complex; the correlation of the structures of crown ether complexes in the solid state and in solution

David Reinhoudt, H.J. den Hertog, F. de Jong

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Abstract

Single-crystal X-ray analysis of the 5′-bromo-1′,3′-xylyl-18-crown-5· tert-butylammonium hexafluorophosphate complex shows that the complex is of the “nesting” type in which the cation and the aryl group are on the same face of the macroring and that the macroring has a (ag+a) (ag−a) (ag+a) (ag−a)(ag+a) (ag−a) conformation.
Original languageUndefined
Pages (from-to)2513-2516
JournalTetrahedron letters
Volume22
Issue number8
DOIs
Publication statusPublished - 1981

Keywords

  • IR-68890

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