A novel type of stereoisomerism in calix[4]arene-based carceplexes

Peter Timmerman, Willem Verboom, Frank C.J.M. van Veggel, John P.M. van Duynhoven, David N. Reinhoudt

Research output: Contribution to journalArticleAcademicpeer-review

155 Citations (Scopus)
63 Downloads (Pure)

Abstract

Different orientations of the guest in the cavity of a carcerand lead to a new type of stereoisomerism, “carceroisomerism”. The structure of the host–guest compound (which is shown on the cover of this issue) and its dynamic behavior was studied in detail by NMR methods. Such compounds could perhaps find application as molecular switches for electronic devices.
Original languageEnglish
Pages (from-to)2345-2348
JournalAngewandte Chemie, International Edition in English
Volume33
Issue number22
DOIs
Publication statusPublished - 1994

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