A novel type of stereoisomerism in calix[4]arene-based carceplexes

Peter Timmerman; Willem Verboom; Frank C.J.M. van Veggel; John P.M. van Duynhoven; David N. Reinhoudt

doi:10.1002/anie.199423451

A novel type of stereoisomerism in calix[4]arene-based carceplexes

Peter Timmerman
, Willem Verboom
, Frank C.J.M. van Veggel
, John P.M. van Duynhoven
, David N. Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

162 Citations (Scopus)

395 Downloads (Pure)

Abstract

Different orientations of the guest in the cavity of a carcerand lead to a new type of stereoisomerism, “carceroisomerism”. The structure of the host–guest compound (which is shown on the cover of this issue) and its dynamic behavior was studied in detail by NMR methods. Such compounds could perhaps find application as molecular switches for electronic devices.

Original language	English
Pages (from-to)	2345-2348
Journal	Angewandte Chemie, International Edition in English
Volume	33
Issue number	22
DOIs	https://doi.org/10.1002/anie.199423451
Publication status	Published - 1994

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title = "A novel type of stereoisomerism in calix[4]arene-based carceplexes",

abstract = "Different orientations of the guest in the cavity of a carcerand lead to a new type of stereoisomerism, “carceroisomerism”. The structure of the host–guest compound (which is shown on the cover of this issue) and its dynamic behavior was studied in detail by NMR methods. Such compounds could perhaps find application as molecular switches for electronic devices.",

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AU - van Duynhoven, John P.M.

AU - Reinhoudt, David N.

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AB - Different orientations of the guest in the cavity of a carcerand lead to a new type of stereoisomerism, “carceroisomerism”. The structure of the host–guest compound (which is shown on the cover of this issue) and its dynamic behavior was studied in detail by NMR methods. Such compounds could perhaps find application as molecular switches for electronic devices.

U2 - 10.1002/anie.199423451

DO - 10.1002/anie.199423451

M3 - Article

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A novel type of stereoisomerism in calix[4]arene-based carceplexes

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