A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

J. Scheele; P. Timmerman; David Reinhoudt

doi:10.1039/a806722h

A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

J. Scheele, P. Timmerman, David Reinhoudt

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Abstract

Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.

Original language	Undefined
Pages (from-to)	2613-2614
Journal	Chemical communications
Volume	1998
Issue number	23
DOIs	https://doi.org/10.1039/a806722h
Publication status	Published - 1998

Keywords

METIS-105973
IR-11058

Access to Document

10.1039/a806722h

Cite this

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title = "A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes",

abstract = "Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.",

keywords = "METIS-105973, IR-11058",

author = "J. Scheele and P. Timmerman and David Reinhoudt",

year = "1998",

doi = "10.1039/a806722h",

language = "Undefined",

volume = "1998",

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journal = "Chemical communications",

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publisher = "Royal Society of Chemistry",

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T1 - A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

AU - Scheele, J.

AU - Timmerman, P.

AU - Reinhoudt, David

PY - 1998

Y1 - 1998

N2 - Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.

AB - Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.

KW - METIS-105973

KW - IR-11058

U2 - 10.1039/a806722h

DO - 10.1039/a806722h

M3 - Article

SN - 1359-7345

VL - 1998

SP - 2613

EP - 2614

JO - Chemical communications

JF - Chemical communications

IS - 23

ER -