A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

J. Scheele, P. Timmerman, David Reinhoudt

    Research output: Contribution to journalArticleAcademicpeer-review

    41 Citations (Scopus)

    Abstract

    Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.
    Original languageUndefined
    Pages (from-to)2613-2614
    JournalChemical communications
    Volume1998
    Issue number23
    DOIs
    Publication statusPublished - 1998

    Keywords

    • METIS-105973
    • IR-11058

    Cite this

    @article{6f556ae2dd6b4683ac498462a6f1b3f1,
    title = "A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes",
    abstract = "Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.",
    keywords = "METIS-105973, IR-11058",
    author = "J. Scheele and P. Timmerman and David Reinhoudt",
    year = "1998",
    doi = "10.1039/a806722h",
    language = "Undefined",
    volume = "1998",
    pages = "2613--2614",
    journal = "Chemical communications",
    issn = "1359-7345",
    publisher = "Royal Society of Chemistry",
    number = "23",

    }

    A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes. / Scheele, J.; Timmerman, P.; Reinhoudt, David.

    In: Chemical communications, Vol. 1998, No. 23, 1998, p. 2613-2614.

    Research output: Contribution to journalArticleAcademicpeer-review

    TY - JOUR

    T1 - A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

    AU - Scheele, J.

    AU - Timmerman, P.

    AU - Reinhoudt, David

    PY - 1998

    Y1 - 1998

    N2 - Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.

    AB - Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.

    KW - METIS-105973

    KW - IR-11058

    U2 - 10.1039/a806722h

    DO - 10.1039/a806722h

    M3 - Article

    VL - 1998

    SP - 2613

    EP - 2614

    JO - Chemical communications

    JF - Chemical communications

    SN - 1359-7345

    IS - 23

    ER -