A study of slow pyrolysis of one low rank coal via pyrolysis-GC/MS

C. Lievens, Donghui Ci, Yu Bai, Linge Ma, Rui Zhang, Jing Yun Chen, Qingqing Gai, Yinhua Long, Xiaofen Guo*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

66 Citations (Scopus)

Abstract

This paper describes the study of one low rank coal (LRC). To investigate its molecular structure, a LRC was characterized by proximate and ultimate analyses, XRD, FTIR, Raman spectroscopy, and pyrolysis-GC/MS (py-GC/MS). The light volatile fraction of LRC was characterized via py-GC/MS. LRC's aromatic ring structures consist of 59% amorphous structures, 22% of highly ordered structures with no less than 6 rings, 16% of aromatic structures characterized by aliphatic and/or ether substitutions and 3% of substituted benzene rings. XRD results show that the crystalline unit of LRC contains 1.44 aromatic carbon atoms per aliphatic carbon atom. Aromatic cluster structures within LRC are interconnected via ether- and covalent CC bonds. Hydroxyl, ether and carbonyl functionalities give LRC its polar character. The slow pyrolysis of LRC resulted in a light volatile GC/MS detected fraction consisting of 20% aromatic ring compounds, 45% of phenolics, 30% of aliphatic hydrocarbons and 5% O-compounds, of which the concentration, evolution and nature were dependent on the heating rates and end temperatures. Generally, slow pyrolysis of LRC at 700 C yielded the highest concentrations of unsaturated acyclic hydrocarbons, aromatics and phenolics.

Original languageEnglish
Pages (from-to)85-93
Number of pages9
JournalFuel processing technology
Volume116
Early online date27 May 2013
DOIs
Publication statusPublished - Dec 2013
Externally publishedYes

Keywords

  • Coal structure
  • Coal volatile fraction
  • Low rank coal
  • py-GC/MS
  • ITC-ISI-JOURNAL-ARTICLE

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