A theoretical and experimental study on solubility of curatives in rubbers

Rui Guo; Auke G. Talma; Rabin N. Datta; Wilma K. Dierkes; Jacques W.M. Noordermeer

doi:10.1002/mame.200800370

A theoretical and experimental study on solubility of curatives in rubbers

Rui Guo, Auke G. Talma, Rabin N. Datta, Wilma K. Dierkes, Jacques W.M. Noordermeer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

7 Citations (Scopus)

2 Downloads (Pure)

Abstract

The current study provides indications for improving the properties of dissimilar rubber blends. As solubility is a key factor for the distribution and a driving force for the migration of curatives in dissimilar rubber blends, it is of importance to have precise data of their solubilities. The solubilities of (insoluble) sulfur and the accelerators CBS, MBT and DCBS are measured at RT and at 60 °C, in lightly crosslinked SBR, NBR and EPDM. The experimental results correlate well with calculated solubility parameters, as determined using the method of Hoftijzer and van Krevelen.

Original language	English
Pages (from-to)	330-335
Journal	Macromolecular materials and engineering
Volume	294
Issue number	5
DOIs	https://doi.org/10.1002/mame.200800370
Publication status	Published - 2009

Keywords

Vulcanization
Curing of polymers
Rubber
Blends

Access to Document

10.1002/mame.200800370Licence: CC BY

ArticleFinal published version, 373 KBLicence: CC BY

Cite this

@article{fd2e157fef1b4d6ca82e7c8bd6fcdd7a,

title = "A theoretical and experimental study on solubility of curatives in rubbers",

abstract = "The current study provides indications for improving the properties of dissimilar rubber blends. As solubility is a key factor for the distribution and a driving force for the migration of curatives in dissimilar rubber blends, it is of importance to have precise data of their solubilities. The solubilities of (insoluble) sulfur and the accelerators CBS, MBT and DCBS are measured at RT and at 60 °C, in lightly crosslinked SBR, NBR and EPDM. The experimental results correlate well with calculated solubility parameters, as determined using the method of Hoftijzer and van Krevelen.",

keywords = "Vulcanization, Curing of polymers, Rubber, Blends",

author = "Rui Guo and Talma, {Auke G.} and Datta, {Rabin N.} and Dierkes, {Wilma K.} and Noordermeer, {Jacques W.M.}",

year = "2009",

doi = "10.1002/mame.200800370",

language = "English",

volume = "294",

pages = "330--335",

journal = "Macromolecular materials and engineering",

issn = "1438-7492",

publisher = "Wiley-VCH Verlag",

number = "5",

}

TY - JOUR

T1 - A theoretical and experimental study on solubility of curatives in rubbers

AU - Guo, Rui

AU - Talma, Auke G.

AU - Datta, Rabin N.

AU - Dierkes, Wilma K.

AU - Noordermeer, Jacques W.M.

PY - 2009

Y1 - 2009

N2 - The current study provides indications for improving the properties of dissimilar rubber blends. As solubility is a key factor for the distribution and a driving force for the migration of curatives in dissimilar rubber blends, it is of importance to have precise data of their solubilities. The solubilities of (insoluble) sulfur and the accelerators CBS, MBT and DCBS are measured at RT and at 60 °C, in lightly crosslinked SBR, NBR and EPDM. The experimental results correlate well with calculated solubility parameters, as determined using the method of Hoftijzer and van Krevelen.

AB - The current study provides indications for improving the properties of dissimilar rubber blends. As solubility is a key factor for the distribution and a driving force for the migration of curatives in dissimilar rubber blends, it is of importance to have precise data of their solubilities. The solubilities of (insoluble) sulfur and the accelerators CBS, MBT and DCBS are measured at RT and at 60 °C, in lightly crosslinked SBR, NBR and EPDM. The experimental results correlate well with calculated solubility parameters, as determined using the method of Hoftijzer and van Krevelen.

KW - Vulcanization

KW - Curing of polymers

KW - Rubber

KW - Blends

U2 - 10.1002/mame.200800370

DO - 10.1002/mame.200800370

M3 - Article

VL - 294

SP - 330

EP - 335

JO - Macromolecular materials and engineering

JF - Macromolecular materials and engineering

SN - 1438-7492

IS - 5

ER -

A theoretical and experimental study on solubility of curatives in rubbers

Abstract

Keywords

Access to Document

Fingerprint

Cite this