Alkane Activation at Ambient Temperatures: Unusual Selectivities, C-C, C-H Bond Scission versus C-C Bond Coupling

C. Trionfetti; A. Agiral; Johannes G.E. Gardeniers; Leonardus Lefferts; Kulathuiyer Seshan

doi:10.1002/cphc.200700757

Alkane Activation at Ambient Temperatures: Unusual Selectivities, C-C, C-H Bond Scission versus C-C Bond Coupling

C. Trionfetti, A. Agiral, Johannes G.E. Gardeniers, Leonardus Lefferts, Kulathuiyer Seshan

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

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Abstract

Activating bonds: A cold plasma generated by dielectric barrier discharge in a microreactor converts alkanes (C1–C3) at atmospheric pressure. Large amounts of products with higher molecular weight than the starting hydrocarbons are observed showing that C-H activation at lower T favourably leads to C-C bond formation.

Original language	Undefined
Pages (from-to)	533-537
Number of pages	5
Journal	ChemPhysChem
Volume	9
Issue number	4
DOIs	https://doi.org/10.1002/cphc.200700757 https://doi.org/10.1002/cphp.200700757
Publication status	Published - 2008

Keywords

METIS-246851
IR-72567

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Cite this

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abstract = "Activating bonds: A cold plasma generated by dielectric barrier discharge in a microreactor converts alkanes (C1–C3) at atmospheric pressure. Large amounts of products with higher molecular weight than the starting hydrocarbons are observed showing that C-H activation at lower T favourably leads to C-C bond formation.",

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AU - Agiral, A.

AU - Gardeniers, Johannes G.E.

AU - Lefferts, Leonardus

AU - Seshan, Kulathuiyer

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AB - Activating bonds: A cold plasma generated by dielectric barrier discharge in a microreactor converts alkanes (C1–C3) at atmospheric pressure. Large amounts of products with higher molecular weight than the starting hydrocarbons are observed showing that C-H activation at lower T favourably leads to C-C bond formation.

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KW - IR-72567

U2 - 10.1002/cphc.200700757

DO - 10.1002/cphc.200700757

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