Amplification of Chirality in Hydrogen-Bonded Tetrarosette Helices

Miguel Mateos timoneda, Mercedes Crego Calama, David Reinhoudt

Research output: Contribution to journalArticleAcademicpeer-review

18 Citations (Scopus)

Abstract

The amplification of chirality in hydrogen-bonded tetrarosette assemblies under thermodynamic equilibrium is described. The extent of the chiral amplification obtained by means of “sergeants-and-soldiers” experiments depends only on the structure of the assembly and it is independent of the methodology used for the formation of the tetrarosette assemblies. The difference in free energy (Δ) between the M- and P-diastereomeric helices is up to 40 times higher than for double rosette assemblies.
Original languageEnglish
Pages (from-to)2630-2638
Number of pages9
JournalChemistry: a European journal
Volume12
Issue number9
DOIs
Publication statusPublished - 2006

Keywords

  • Self-Assembly
  • supramolecular chirality
  • Hydrogen bonds
  • Chiral amplification
  • IR-72193

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