Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers

Simon Flink; Frank C.J.M. van Veggel; David N. Reinhoudt

doi:10.1007/978-94-011-5010-1_48

Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers

Simon Flink
, Frank C.J.M. van Veggel
, David N. Reinhoudt

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

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Abstract

The reversible binding of cations to self-assembled monolayers of (6-mercaptohexyloxy) methyl-12-crown-4 (1) and (6-mercaptohexyloxy)methyl-15-crown-5 (2) in aqueous solutions is reported. Binding of the electrochemically inactive cations can be monitored by cyclic voltammetry and impedance spectroscopy using Ru(NH₃)₆ ^2+/3+ as “reporter ions”. As a result of the high surface density of crown ether ligands sandwich complexes are probably formed, which accounts for the observed selectivities of the monolayer.

Original language	English
Title of host publication	Sensor technology in the Netherlands - state of the art
Subtitle of host publication	proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands
Editors	A. van den Berg, P. Bergveld
Place of Publication	Dordrecht
Publisher	Kluwer Academic Publishers
Pages	299-304
ISBN (Electronic)	978-94-011-5010-1
ISBN (Print)	978-94-010-6103-2
DOIs	https://doi.org/10.1007/978-94-011-5010-1_48
Publication status	Published - 1998
Event	Dutch Sensor Conference 1998: Sensor Technology in the Netherlands: State of the Art - University of Twente, Enschede, Netherlands Duration: 2 Mar 1998 → 3 Mar 1998

Publication series

Name	MESA monographs
Publisher	Kluwer Academic Publishers
Volume	2

Conference

Conference	Dutch Sensor Conference 1998
Country/Territory	Netherlands
City	Enschede
Period	2/03/98 → 3/03/98

Keywords

Cyclic voltammetry
Crown ether
Charge transfer resistance
Recede contact angle
Glycol monomethyl ether

Access to Document

10.1007/978-94-011-5010-1_48

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Flink, S., van Veggel, F. C. J. M., & Reinhoudt, D. N. (1998). Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. In A. van den Berg, & P. Bergveld (Eds.), Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands (pp. 299-304). (MESA monographs; Vol. 2). Kluwer Academic Publishers. https://doi.org/10.1007/978-94-011-5010-1_48

Flink, Simon ; van Veggel, Frank C.J.M. ; Reinhoudt, David N. / Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. editor / A. van den Berg ; P. Bergveld. Dordrecht : Kluwer Academic Publishers, 1998. pp. 299-304 (MESA monographs).

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title = "Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers",

abstract = "The reversible binding of cations to self-assembled monolayers of (6-mercaptohexyloxy) methyl-12-crown-4 (1) and (6-mercaptohexyloxy)methyl-15-crown-5 (2) in aqueous solutions is reported. Binding of the electrochemically inactive cations can be monitored by cyclic voltammetry and impedance spectroscopy using Ru(NH3)6 2+/3+ as “reporter ions”. As a result of the high surface density of crown ether ligands sandwich complexes are probably formed, which accounts for the observed selectivities of the monolayer.",

keywords = "Cyclic voltammetry, Crown ether, Charge transfer resistance, Recede contact angle, Glycol monomethyl ether",

author = "Simon Flink and \{van Veggel\}, \{Frank C.J.M.\} and Reinhoudt, \{David N.\}",

year = "1998",

doi = "10.1007/978-94-011-5010-1\_48",

language = "English",

isbn = "978-94-010-6103-2",

series = "MESA monographs",

publisher = "Kluwer Academic Publishers",

pages = "299--304",

editor = "\{van den Berg\}, A. and P. Bergveld",

booktitle = "Sensor technology in the Netherlands - state of the art",

address = "Netherlands",

note = "Dutch Sensor Conference 1998 : Sensor Technology in the Netherlands: State of the Art ; Conference date: 02-03-1998 Through 03-03-1998",

}

Flink, S, van Veggel, FCJM & Reinhoudt, DN 1998, Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. in A van den Berg & P Bergveld (eds), Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. MESA monographs, vol. 2, Kluwer Academic Publishers, Dordrecht, pp. 299-304, Dutch Sensor Conference 1998, Enschede, Netherlands, 2/03/98. https://doi.org/10.1007/978-94-011-5010-1_48

Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. / Flink, Simon; van Veggel, Frank C.J.M.; Reinhoudt, David N.
Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. ed. / A. van den Berg; P. Bergveld. Dordrecht: Kluwer Academic Publishers, 1998. p. 299-304 (MESA monographs; Vol. 2).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

TY - CHAP

T1 - Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers

AU - Flink, Simon

AU - van Veggel, Frank C.J.M.

AU - Reinhoudt, David N.

PY - 1998

Y1 - 1998

N2 - The reversible binding of cations to self-assembled monolayers of (6-mercaptohexyloxy) methyl-12-crown-4 (1) and (6-mercaptohexyloxy)methyl-15-crown-5 (2) in aqueous solutions is reported. Binding of the electrochemically inactive cations can be monitored by cyclic voltammetry and impedance spectroscopy using Ru(NH3)6 2+/3+ as “reporter ions”. As a result of the high surface density of crown ether ligands sandwich complexes are probably formed, which accounts for the observed selectivities of the monolayer.

AB - The reversible binding of cations to self-assembled monolayers of (6-mercaptohexyloxy) methyl-12-crown-4 (1) and (6-mercaptohexyloxy)methyl-15-crown-5 (2) in aqueous solutions is reported. Binding of the electrochemically inactive cations can be monitored by cyclic voltammetry and impedance spectroscopy using Ru(NH3)6 2+/3+ as “reporter ions”. As a result of the high surface density of crown ether ligands sandwich complexes are probably formed, which accounts for the observed selectivities of the monolayer.

KW - Cyclic voltammetry

KW - Crown ether

KW - Charge transfer resistance

KW - Recede contact angle

KW - Glycol monomethyl ether

U2 - 10.1007/978-94-011-5010-1_48

DO - 10.1007/978-94-011-5010-1_48

M3 - Chapter

SN - 978-94-010-6103-2

T3 - MESA monographs

SP - 299

EP - 304

BT - Sensor technology in the Netherlands - state of the art

A2 - van den Berg, A.

A2 - Bergveld, P.

PB - Kluwer Academic Publishers

CY - Dordrecht

T2 - Dutch Sensor Conference 1998

Y2 - 2 March 1998 through 3 March 1998

ER -

Flink S, van Veggel FCJM, Reinhoudt DN. Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. In van den Berg A, Bergveld P, editors, Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. Dordrecht: Kluwer Academic Publishers. 1998. p. 299-304. (MESA monographs). doi: 10.1007/978-94-011-5010-1_48

Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers

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