Bis(2-phenyl­ethyl­ammonium) tetra­aqua­dichloridonickel(II) dichloride dihydrate

Anne H. Arkenbout, Auke Meetsma, Thom T.M. Palstra

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1 Citation (Scopus)

Abstract

The crystal structure of the title compound, (C8H9NH3)2[NiCl2(H2O)4]Cl2·2H2O, was determined at 100 K. The nickel(II) ion is surrounded by an octa­hedron in which four water mol­ecules and two Cl atoms are coordinated. These freestanding octa­hedra form a hydrogen-bonding network with the ammonium group of the 2-phenyl­ethyl­ammonium cations and the solvent water molecules and chloride ions. This results in sheets of freestanding octa­hedra alternating with layers of organic material.
Original languageEnglish
Number of pages16
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number2421
DOIs
Publication statusPublished - 2007
Externally publishedYes

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dichlorides
Ions
Molecules
Water
organic materials
Nickel
Ammonium Compounds
water
Cations
Chlorides
molecules
Hydrogen bonds
ions
Crystal structure
Positive ions
chlorides
nickel
cations
Atoms
crystal structure

Cite this

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title = "Bis(2-phenyl­ethyl­ammonium) tetra­aqua­dichloridonickel(II) dichloride dihydrate",
abstract = "The crystal structure of the title compound, (C8H9NH3)2[NiCl2(H2O)4]Cl2·2H2O, was determined at 100 K. The nickel(II) ion is surrounded by an octa­hedron in which four water mol­ecules and two Cl atoms are coordinated. These freestanding octa­hedra form a hydrogen-bonding network with the ammonium group of the 2-phenyl­ethyl­ammonium cations and the solvent water molecules and chloride ions. This results in sheets of freestanding octa­hedra alternating with layers of organic material.",
author = "Arkenbout, {Anne H.} and Auke Meetsma and Palstra, {Thom T.M.}",
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language = "English",
volume = "63",
journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
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Bis(2-phenyl­ethyl­ammonium) tetra­aqua­dichloridonickel(II) dichloride dihydrate. / Arkenbout, Anne H.; Meetsma, Auke; Palstra, Thom T.M. .

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 2421, 2007.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Bis(2-phenyl­ethyl­ammonium) tetra­aqua­dichloridonickel(II) dichloride dihydrate

AU - Arkenbout, Anne H.

AU - Meetsma, Auke

AU - Palstra, Thom T.M.

PY - 2007

Y1 - 2007

N2 - The crystal structure of the title compound, (C8H9NH3)2[NiCl2(H2O)4]Cl2·2H2O, was determined at 100 K. The nickel(II) ion is surrounded by an octa­hedron in which four water mol­ecules and two Cl atoms are coordinated. These freestanding octa­hedra form a hydrogen-bonding network with the ammonium group of the 2-phenyl­ethyl­ammonium cations and the solvent water molecules and chloride ions. This results in sheets of freestanding octa­hedra alternating with layers of organic material.

AB - The crystal structure of the title compound, (C8H9NH3)2[NiCl2(H2O)4]Cl2·2H2O, was determined at 100 K. The nickel(II) ion is surrounded by an octa­hedron in which four water mol­ecules and two Cl atoms are coordinated. These freestanding octa­hedra form a hydrogen-bonding network with the ammonium group of the 2-phenyl­ethyl­ammonium cations and the solvent water molecules and chloride ions. This results in sheets of freestanding octa­hedra alternating with layers of organic material.

U2 - 10.1107/S160053680704130X

DO - 10.1107/S160053680704130X

M3 - Article

VL - 63

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 2421

ER -