Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81

W.I. Iwema Bakker; D.N. Reinhoudt

doi:10.1007/978-94-011-3654-9_20

Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81

W.I. Iwema Bakker, D.N. Reinhoudt

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic

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Abstract

For the use in medicine we are interested in ligands that form kinetically stable complexes with radioactive alkali cations. The spherands form very stable complexes with Li+ and Na+, but reject the larger alkali cations like K+ and Rb+. Our objective was to synthesize macrocyclic hosts based on a m-teranisyl unit and a calix[4]arene moiety that form kinetically stable complexes not only with Na+ and K+ but also with Rb+.

Original language	English
Title of host publication	New Separation Chemistry Techniques for Radioactive Waste and Other Specific Applications
Editors	Messrs L. Cecille, M. Casara, L. Pietrelli
Place of Publication	Dordrecht
Publisher	Elsevier
Pages	142-149
Number of pages	8
ISBN (Electronic)	978-94-011-3654-9
ISBN (Print)	978-1-85166-656-0
DOIs	https://doi.org/10.1007/978-94-011-3654-9_20
Publication status	Published - 1991

Keywords

IR-12997
METIS-107178
Crown ethers
Stable complex
Partial cone
Alkali cation
Picrate anion

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10.1007/978-94-011-3654-9_20

IwemaBakker1991calixspherandsFinal published version, 259 KB

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title = "Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81",

abstract = "For the use in medicine we are interested in ligands that form kinetically stable complexes with radioactive alkali cations. The spherands form very stable complexes with Li+ and Na+, but reject the larger alkali cations like K+ and Rb+. Our objective was to synthesize macrocyclic hosts based on a m-teranisyl unit and a calix[4]arene moiety that form kinetically stable complexes not only with Na+ and K+ but also with Rb+.",

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Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81. / Iwema Bakker, W.I.; Reinhoudt, D.N.

New Separation Chemistry Techniques for Radioactive Waste and Other Specific Applications. ed. / Messrs L. Cecille; M. Casara; L. Pietrelli. Dordrecht : Elsevier, 1991. p. 142-149.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic

TY - CHAP

T1 - Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81

AU - Iwema Bakker, W.I.

AU - Reinhoudt, D.N.

PY - 1991

Y1 - 1991

N2 - For the use in medicine we are interested in ligands that form kinetically stable complexes with radioactive alkali cations. The spherands form very stable complexes with Li+ and Na+, but reject the larger alkali cations like K+ and Rb+. Our objective was to synthesize macrocyclic hosts based on a m-teranisyl unit and a calix[4]arene moiety that form kinetically stable complexes not only with Na+ and K+ but also with Rb+.

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KW - IR-12997

KW - METIS-107178

KW - Crown ethers

KW - Stable complex

KW - Partial cone

KW - Alkali cation

KW - Picrate anion

U2 - 10.1007/978-94-011-3654-9_20

DO - 10.1007/978-94-011-3654-9_20

M3 - Chapter

SN - 978-1-85166-656-0

SP - 142

EP - 149

BT - New Separation Chemistry Techniques for Radioactive Waste and Other Specific Applications

A2 - Cecille, Messrs L.

A2 - Casara, M.

A2 - Pietrelli, L.

PB - Elsevier

CY - Dordrecht

ER -

Calixspherands as Ligands for the Complexation of Radioactive Rubidium—81

Abstract

Keywords

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