Carbon nano-fiber based membrane reactor for selective nitrite hydrogenation

Roger Brunet Espinosa, D. Rafieian, Rob G.H. Lammertink, Leonardus Lefferts

Research output: Contribution to journalArticleAcademicpeer-review

11 Citations (Scopus)
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Abstract

Catalytic hydrogenation of nitrite in drinking water demands control over the selectivity towards nitrogen, minimizing the formation of ammonia. This selectivity is strongly influenced by the H/N ratio of reaction intermediates at the catalyst surface. Therefore, we fabricated a membrane reactor that feeds separately hydrogen gas and a nitrite solution. This allows dosing low but homogeneous hydrogen concentrations along the axial direction of the catalyst bed. As a consequence, low H/N ratios can be achieved, favouring the formation of nitrogen without limiting the nitrite conversion. We demonstrate that this reactor concept offers better nitrogen selectivity than conventional reactor configurations where hydrogen is pre-dissolved in the nitrite solution.
Original languageEnglish
Pages (from-to)50-61
Number of pages12
JournalCatalysis today
Volume273
DOIs
Publication statusPublished - 2016

Keywords

  • IR-100554
  • METIS-319158

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