TY - JOUR
T1 - Catalytic hydrogenolysis of saccharides : Part I. Qualitative and quantitative methods for the identification and determination of the reaction products
AU - van Ling, G.
AU - Ruijterman, C.
AU - Vlugter, J.C.
PY - 1967
Y1 - 1967
N2 - The numerous, chemical reactions (hydrolysis, cracking, hydrogenation), occurring during the catalytic hydrogenolysis of saccharides, result in a ulticomponent mixture, consisting mainly of polyhydric alcohols. These alcohols, in general, have high boiling points and a poor thermostability. Separation of the individual components by high-vacuum distillation requires a relatively high temperature that causes dehydration, condensation, and charring. Qualitative paper chromatographic and quantitative gas-liquid chromatographic methods of analysis have therefore been developed; these provide useful tools for further studies on reaction mechanisms and reaction kinetics of the hydrogenolysis of saccharides.
AB - The numerous, chemical reactions (hydrolysis, cracking, hydrogenation), occurring during the catalytic hydrogenolysis of saccharides, result in a ulticomponent mixture, consisting mainly of polyhydric alcohols. These alcohols, in general, have high boiling points and a poor thermostability. Separation of the individual components by high-vacuum distillation requires a relatively high temperature that causes dehydration, condensation, and charring. Qualitative paper chromatographic and quantitative gas-liquid chromatographic methods of analysis have therefore been developed; these provide useful tools for further studies on reaction mechanisms and reaction kinetics of the hydrogenolysis of saccharides.
KW - IR-68098
U2 - 10.1016/S0008-6215(00)80195-0
DO - 10.1016/S0008-6215(00)80195-0
M3 - Article
SN - 0008-6215
VL - 4
SP - 380
EP - 386
JO - Carbohydrate Research
JF - Carbohydrate Research
IS - 5
ER -