Catalytic Performance of Pd Nanoparticles Obtained by Direct Reduction in Cellulose– Poly(ferrocenylsilane) Hybrid Sponges

Huan Cheng, Mark A. Hempenius, Xiaofeng Sui*, Julius Vancso

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

8 Citations (Scopus)
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Abstract

Cellulose–poly(ferrocenylsilane) (PFS) polyionic liquid (PIL) composite sponges are fabricated by codissolution of cellulose and PFS-PIL, followed by solvent exchange and freeze-drying. The hybrid sponges are used to in situ produce and immobilize palladium nanoparticles (Pd NPs), leading to Pd NP-decorated porous supports. The formation of Pd NPs is confirmed by TEM and XPS measurements. The as-prepared cellulose/PFS-PIL@Pd sponges exhibit a high catalytic activity in the reduction of 4-nitrophenol (4-NiP) to 4-aminophenol (4-AmP). As a variety of metal NPs may be immobilized using this method, these sponges constitute a promising new class of catalytic porous supports.
Original languageEnglish
Article number2101664
JournalAdvanced materials interfaces
Volume9
Issue number6
Early online date30 Jan 2022
DOIs
Publication statusPublished - 22 Feb 2022

Keywords

  • UT-Hybrid-D

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