Cavity effect of calix[4]arenes in electrophilic aromatic substitution reactions

Oliver Struck; John P.M. van Duynhoven; Willem Verboom; Sybolt Harkema; David N. Reinhoudt

doi:10.1039/CC9960001517

Cavity effect of calix[4]arenes in electrophilic aromatic substitution reactions

Oliver Struck, John P.M. van Duynhoven, Willem Verboom, Sybolt Harkema, David N. Reinhoudt

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Abstract

Electrophilic aromatic substitutions of hydroxymethylcalix[4]arenas with monosubstituted benzene derivatives give rise to very unusual ortho-selectivities caused by a cavity effect of the calix[4]arenas.

Original language	English
Pages (from-to)	1517-1518
Journal	Chemical communications
Volume	1996
Issue number	13
DOIs	https://doi.org/10.1039/CC9960001517
Publication status	Published - 1996

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@article{0e2ebef2d7414a2f9dcf612843defc2b,

title = "Cavity effect of calix[4]arenes in electrophilic aromatic substitution reactions",

abstract = "Electrophilic aromatic substitutions of hydroxymethylcalix[4]arenas with monosubstituted benzene derivatives give rise to very unusual ortho-selectivities caused by a cavity effect of the calix[4]arenas.",

author = "Oliver Struck and {van Duynhoven}, {John P.M.} and Willem Verboom and Sybolt Harkema and Reinhoudt, {David N.}",

year = "1996",

doi = "10.1039/CC9960001517",

language = "English",

volume = "1996",

pages = "1517--1518",

journal = "Chemical communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

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TY - JOUR

T1 - Cavity effect of calix[4]arenes in electrophilic aromatic substitution reactions

AU - Struck, Oliver

AU - van Duynhoven, John P.M.

AU - Verboom, Willem

AU - Harkema, Sybolt

AU - Reinhoudt, David N.

PY - 1996

Y1 - 1996

N2 - Electrophilic aromatic substitutions of hydroxymethylcalix[4]arenas with monosubstituted benzene derivatives give rise to very unusual ortho-selectivities caused by a cavity effect of the calix[4]arenas.

AB - Electrophilic aromatic substitutions of hydroxymethylcalix[4]arenas with monosubstituted benzene derivatives give rise to very unusual ortho-selectivities caused by a cavity effect of the calix[4]arenas.

U2 - 10.1039/CC9960001517

DO - 10.1039/CC9960001517

M3 - Article

SN - 1359-7345

VL - 1996

SP - 1517

EP - 1518

JO - Chemical communications

JF - Chemical communications

IS - 13

ER -

Cavity effect of calix[4]arenes in electrophilic aromatic substitution reactions

Abstract

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