Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response

Sinem Tas; Maciej Kopec; Rianne van der Pol; Marco Cirelli; Ilse de Vries; Deniz A. Bölükbas; Kristianne Tempelman; Nieck E. Benes; Mark A. Hempenius; G. Julius Vancso; Sissi de Beer

doi:10.1002/macp.201800537

Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response

Sinem Tas^* (Corresponding Author), Maciej Kopec, Rianne van der Pol, Marco Cirelli, Ilse de Vries, Deniz A. Bölükbas, Kristianne Tempelman, Nieck E. Benes, Mark A. Hempenius, G. Julius Vancso, Sissi de Beer

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Herein is described the switchable fluorescence response of poly(methyl methacrylate) (PMMA) brushes. Chain end fluorescein labeled PMMA brushes are prepared by combining surface-initiated atom transfer radical polymerization (SI-ATRP) with a copper-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction. Successful attachment of fluorescein is confirmed by measuring fluorescence of the as-prepared films. Utilizing co-solvency of PMMA in isopropanol-water mixtures, responsive behavior of the end-functionalized brushes is demonstrated by measuring the changes in fluorescence intensity between the swollen and collapsed states.

Original language	English
Article number	1800537
Journal	Macromolecular chemistry and physics
Volume	220
Issue number	5
DOIs	https://doi.org/10.1002/macp.201800537
Publication status	Published - 1 Mar 2019

Keywords

UT-Hybrid-D
fluorescent polymers
polymer brushes
solvent responsiveness
co-solvency

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10.1002/macp.201800537

Tas_et_al-2019-Macromolecular_Chemistry_and_PhysicsFinal published version, 1.16 MBLicence: Taverne

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title = "Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response",

abstract = "Herein is described the switchable fluorescence response of poly(methyl methacrylate) (PMMA) brushes. Chain end fluorescein labeled PMMA brushes are prepared by combining surface-initiated atom transfer radical polymerization (SI-ATRP) with a copper-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction. Successful attachment of fluorescein is confirmed by measuring fluorescence of the as-prepared films. Utilizing co-solvency of PMMA in isopropanol-water mixtures, responsive behavior of the end-functionalized brushes is demonstrated by measuring the changes in fluorescence intensity between the swollen and collapsed states.",

keywords = "UT-Hybrid-D, fluorescent polymers, polymer brushes, solvent responsiveness, co-solvency",

author = "Sinem Tas and Maciej Kopec and {van der Pol}, Rianne and Marco Cirelli and {de Vries}, Ilse and B{\"o}l{\"u}kbas, {Deniz A.} and Kristianne Tempelman and Benes, {Nieck E.} and Hempenius, {Mark A.} and Vancso, {G. Julius} and {de Beer}, Sissi",

note = "Wiley deal",

year = "2019",

month = mar,

day = "1",

doi = "10.1002/macp.201800537",

language = "English",

volume = "220",

journal = "Macromolecular chemistry and physics",

issn = "1022-1352",

publisher = "Wiley-VCH Verlag",

number = "5",

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Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response. / Tas, Sinem (Corresponding Author); Kopec, Maciej; van der Pol, Rianne; Cirelli, Marco; de Vries, Ilse; Bölükbas, Deniz A.; Tempelman, Kristianne; Benes, Nieck E.; Hempenius, Mark A.; Vancso, G. Julius ; de Beer, Sissi.

In: Macromolecular chemistry and physics, Vol. 220, No. 5, 1800537, 01.03.2019.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response

AU - Tas, Sinem

AU - Kopec, Maciej

AU - van der Pol, Rianne

AU - Cirelli, Marco

AU - de Vries, Ilse

AU - Bölükbas, Deniz A.

AU - Tempelman, Kristianne

AU - Benes, Nieck E.

AU - Hempenius, Mark A.

AU - Vancso, G. Julius

AU - de Beer, Sissi

N1 - Wiley deal

PY - 2019/3/1

Y1 - 2019/3/1

N2 - Herein is described the switchable fluorescence response of poly(methyl methacrylate) (PMMA) brushes. Chain end fluorescein labeled PMMA brushes are prepared by combining surface-initiated atom transfer radical polymerization (SI-ATRP) with a copper-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction. Successful attachment of fluorescein is confirmed by measuring fluorescence of the as-prepared films. Utilizing co-solvency of PMMA in isopropanol-water mixtures, responsive behavior of the end-functionalized brushes is demonstrated by measuring the changes in fluorescence intensity between the swollen and collapsed states.

AB - Herein is described the switchable fluorescence response of poly(methyl methacrylate) (PMMA) brushes. Chain end fluorescein labeled PMMA brushes are prepared by combining surface-initiated atom transfer radical polymerization (SI-ATRP) with a copper-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction. Successful attachment of fluorescein is confirmed by measuring fluorescence of the as-prepared films. Utilizing co-solvency of PMMA in isopropanol-water mixtures, responsive behavior of the end-functionalized brushes is demonstrated by measuring the changes in fluorescence intensity between the swollen and collapsed states.

KW - UT-Hybrid-D

KW - fluorescent polymers

KW - polymer brushes

KW - solvent responsiveness

KW - co-solvency

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U2 - 10.1002/macp.201800537

DO - 10.1002/macp.201800537

M3 - Article

AN - SCOPUS:85059539454

VL - 220

JO - Macromolecular chemistry and physics

JF - Macromolecular chemistry and physics

SN - 1022-1352

IS - 5

M1 - 1800537

ER -

Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response

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Keywords

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