Characterization of poly(D,L-lactic acid) by gel permeation chromatography

J.A.P.P. van Dijk; J.A.M. Smit; F.E. Kohn; Jan Feijen

doi:10.1002/pol.1983.170210121

Characterization of poly(D,L-lactic acid) by gel permeation chromatography

J.A.P.P. van Dijk, J.A.M. Smit, F.E. Kohn, Jan Feijen

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Abstract

A number of samples of poly(D,L-lactic acid) (PLA) with weight-average molecular weights Ṁw in the range 15,000-350,000 were prepared by a ring-opening polymerization. The molecular weight distributions (MWDs) of these samples were determined by gel permeation chromatography (GPC). The method involves a universal calibration of the columns on the basis of polystyrene standards and a rapid iteration algorithm leading to the establishment of the Mark-Houwink relationship. In addition, osmometry and viscometry data are presented. The effect of hydrolytic degradation on the MWD of two PLA samples was studied by GPC.

Original language	Undefined
Pages (from-to)	197-208
Journal	Journal of Polymer Science: Polymer Chemistry Edition
Volume	21
Issue number	1
DOIs	https://doi.org/10.1002/pol.1983.170210121
Publication status	Published - 1983

Keywords

IR-70784

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10.1002/pol.1983.170210121

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Cite this

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title = "Characterization of poly(D,L-lactic acid) by gel permeation chromatography",

abstract = "A number of samples of poly(D,L-lactic acid) (PLA) with weight-average molecular weights Ṁw in the range 15,000-350,000 were prepared by a ring-opening polymerization. The molecular weight distributions (MWDs) of these samples were determined by gel permeation chromatography (GPC). The method involves a universal calibration of the columns on the basis of polystyrene standards and a rapid iteration algorithm leading to the establishment of the Mark-Houwink relationship. In addition, osmometry and viscometry data are presented. The effect of hydrolytic degradation on the MWD of two PLA samples was studied by GPC.",

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year = "1983",

doi = "10.1002/pol.1983.170210121",

language = "Undefined",

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journal = "Journal of Polymer Science: Polymer Chemistry Edition",

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T1 - Characterization of poly(D,L-lactic acid) by gel permeation chromatography

AU - van Dijk, J.A.P.P.

AU - Smit, J.A.M.

AU - Kohn, F.E.

AU - Feijen, Jan

PY - 1983

Y1 - 1983

N2 - A number of samples of poly(D,L-lactic acid) (PLA) with weight-average molecular weights Ṁw in the range 15,000-350,000 were prepared by a ring-opening polymerization. The molecular weight distributions (MWDs) of these samples were determined by gel permeation chromatography (GPC). The method involves a universal calibration of the columns on the basis of polystyrene standards and a rapid iteration algorithm leading to the establishment of the Mark-Houwink relationship. In addition, osmometry and viscometry data are presented. The effect of hydrolytic degradation on the MWD of two PLA samples was studied by GPC.

AB - A number of samples of poly(D,L-lactic acid) (PLA) with weight-average molecular weights Ṁw in the range 15,000-350,000 were prepared by a ring-opening polymerization. The molecular weight distributions (MWDs) of these samples were determined by gel permeation chromatography (GPC). The method involves a universal calibration of the columns on the basis of polystyrene standards and a rapid iteration algorithm leading to the establishment of the Mark-Houwink relationship. In addition, osmometry and viscometry data are presented. The effect of hydrolytic degradation on the MWD of two PLA samples was studied by GPC.

KW - IR-70784

U2 - 10.1002/pol.1983.170210121

DO - 10.1002/pol.1983.170210121

M3 - Article

VL - 21

SP - 197

EP - 208

JO - Journal of Polymer Science: Polymer Chemistry Edition

JF - Journal of Polymer Science: Polymer Chemistry Edition

SN - 0360-6376

IS - 1

ER -