Chemical Recycling of Used PET by Glycolysis Using Niobia-Based Catalysts

Shadi Shirazimoghaddam, Ihsan Amin, Jimmy A. Faria Albanese, N. Raveendran Shiju*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

Plastic production has steadily increased worldwide at a staggering pace. The polymer industry is, unfortunately, C-intensive, and accumulation of plastics in the environment has become a major issue. Plastic waste valorization into fresh monomers for production of virgin plastics can reduce both the consumption of fossil feedstocks and the environmental pollution, making the plastic economy more sustainable. Recently, the chemical recycling of plastics has been studied as an innovative solution to achieve a fully sustainable cycle. In this way, plastics are depolymerized to their monomers or/and oligomers appropriate for repolymerization, closing the loop. In this work, PET was depolymerized to its bis(2-hydroxyethyl) terephthalate (BHET) monomer via glycolysis, using ethylene glycol (EG) in the presence of niobia-based catalysts. Using a sulfated niobia catalyst treated at 573 K, we obtained 100% conversion of PET and 85% yield toward BHET at 195 °C in 220 min. This approach allows recycling of the PET at reasonable conditions using an inexpensive and nontoxic material as a catalyst.
Original languageEnglish
Pages (from-to)37-44
JournalACS Engineering Au
Volume3
Issue number1
DOIs
Publication statusPublished - 15 Feb 2023

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