Closed Mechanoelectrochemical Cycles of Inidividual Single-Chain Macromolecular Motors by AFM

W. Shi, M.I. Giannotti, Xi Zhang, Mark A. Hempenius, Holger Schönherr, Gyula J. Vancso

Research output: Contribution to journalArticleAcademicpeer-review

58 Citations (Scopus)

Abstract

Motor cycles: Mechanoelectrochemical loops of single-chain macromolecular motors based on individual end-grafted poly(ferrocenyldimethylsilane) are shown by AFM to have an efficiency of up to 26 %. Upon oxidation of a prestretched chain, the chain length increases and the force decreases significantly as a result of intramolecular electrostatic repulsion between oxidized ferrocene units.
Original languageUndefined
Pages (from-to)4800-8404
Number of pages5
JournalAngewandte Chemie, International Edition in English
Volume46
Issue number44
DOIs
Publication statusPublished - 2007

Keywords

  • IR-72217
  • METIS-243272
  • Polymers
  • Electrochemistry
  • Atomic Force Microscopy
  • single-molecule studies
  • molecular motors

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