Competing and simultaneous click reactions at the interface and in solution

Doungporn Yiamsawas, Manfred Wagner, Grit Baier, Katharina Landfester*, Frederik R. Wurm

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

1 Citation (Scopus)
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Abstract

The kinetics of two simultaneous "click" reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive "click" reactions.

Original languageEnglish
Pages (from-to)51327-51331
Number of pages5
JournalRSC advances
Volume6
Issue number56
DOIs
Publication statusPublished - 1 Jan 2016
Externally publishedYes

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