Abstract
The kinetics of two simultaneous "click" reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive "click" reactions.
Original language | English |
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Pages (from-to) | 51327-51331 |
Number of pages | 5 |
Journal | RSC advances |
Volume | 6 |
Issue number | 56 |
DOIs | |
Publication status | Published - 1 Jan 2016 |
Externally published | Yes |