Competing and simultaneous click reactions at the interface and in solution

Doungporn Yiamsawas; Manfred Wagner; Grit Baier; Katharina Landfester; Frederik R. Wurm

doi:10.1039/c6ra08880e

Competing and simultaneous click reactions at the interface and in solution

Doungporn Yiamsawas
, Manfred Wagner
, Grit Baier
, Katharina Landfester^*
, Frederik R. Wurm

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

41 Downloads (Pure)

Abstract

The kinetics of two simultaneous "click" reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive "click" reactions.

Original language	English
Pages (from-to)	51327-51331
Number of pages	5
Journal	RSC advances
Volume	6
Issue number	56
DOIs	https://doi.org/10.1039/c6ra08880e
Publication status	Published - 1 Jan 2016
Externally published	Yes

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Yiamsawas-2016-Competing-and-simultaneous-click-reFinal published version, 619 KBLicence: CC BY

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abstract = "The kinetics of two simultaneous {"}click{"} reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive {"}click{"} reactions.",

author = "Doungporn Yiamsawas and Manfred Wagner and Grit Baier and Katharina Landfester and Wurm, \{Frederik R.\}",

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AU - Wagner, Manfred

AU - Baier, Grit

AU - Landfester, Katharina

AU - Wurm, Frederik R.

PY - 2016/1/1

Y1 - 2016/1/1

N2 - The kinetics of two simultaneous "click" reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive "click" reactions.

AB - The kinetics of two simultaneous "click" reactions (thiol-maleimide addition and thiol-disulfide exchange) were investigated by NMR spectroscopy in homogeneous solution and at the oil/water interface of an inverse miniemulsion. For the polyaddition/-condensation of difunctional reagents it was found that the thiol-disulfide exchange is faster than the thiol-maleimide reaction. The addition of a basic catalyst influences the copolymerization behavior of the competitive "click" reactions.

UR - https://www.scopus.com/pages/publications/84971264701

U2 - 10.1039/c6ra08880e

DO - 10.1039/c6ra08880e

M3 - Article

AN - SCOPUS:84971264701

SN - 2046-2069

VL - 6

SP - 51327

EP - 51331

JO - RSC advances

JF - RSC advances

IS - 56

ER -

Competing and simultaneous click reactions at the interface and in solution

Abstract

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