Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

P.K. Mohapatra, M. Iqbal, D.R. Raut, Willem Verboom, Jurriaan Huskens

Research output: Contribution to journalArticleAcademicpeer-review

53 Citations (Scopus)

Abstract

Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand
Original languageEnglish
Pages (from-to)360-363
Number of pages4
JournalDalton transactions
Volume41
DOIs
Publication statusPublished - 2012

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Actinoid Series Elements
Radioactive Waste
Lanthanoid Series Elements
Complexation
Metal ions
Fluorescence
Ions
Ligands
Lasers

Keywords

  • IR-84646
  • METIS-282349

Cite this

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abstract = "Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand",
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Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies. / Mohapatra, P.K.; Iqbal, M.; Raut, D.R.; Verboom, Willem; Huskens, Jurriaan.

In: Dalton transactions, Vol. 41, 2012, p. 360-363.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

AU - Mohapatra, P.K.

AU - Iqbal, M.

AU - Raut, D.R.

AU - Verboom, Willem

AU - Huskens, Jurriaan

PY - 2012

Y1 - 2012

N2 - Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand

AB - Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand

KW - IR-84646

KW - METIS-282349

U2 - 10.1039/C1DT11561H

DO - 10.1039/C1DT11561H

M3 - Article

VL - 41

SP - 360

EP - 363

JO - Dalton transactions

JF - Dalton transactions

SN - 1477-9226

ER -