Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

P.K. Mohapatra; M. Iqbal; D.R. Raut; Willem Verboom; Jurriaan Huskens

doi:10.1039/C1DT11561H

Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

P.K. Mohapatra
, M. Iqbal
, D.R. Raut
, Willem Verboom
, Jurriaan Huskens

Research output: Contribution to journal › Article › Academic › peer-review

69 Citations (Scopus)

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Abstract

Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand

Original language	English
Pages (from-to)	360-363
Number of pages	4
Journal	Dalton transactions
Volume	41
DOIs	https://doi.org/10.1039/C1DT11561H
Publication status	Published - 2012

Keywords

IR-84646
METIS-282349

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10.1039/C1DT11561H

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title = "Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies",

abstract = "Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand",

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author = "P.K. Mohapatra and M. Iqbal and D.R. Raut and Willem Verboom and Jurriaan Huskens",

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volume = "41",

pages = "360--363",

journal = "Dalton transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

AU - Mohapatra, P.K.

AU - Iqbal, M.

AU - Raut, D.R.

AU - Verboom, Willem

AU - Huskens, Jurriaan

PY - 2012

Y1 - 2012

N2 - Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand

AB - Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand

KW - IR-84646

KW - METIS-282349

U2 - 10.1039/C1DT11561H

DO - 10.1039/C1DT11561H

M3 - Article

SN - 1477-9226

VL - 41

SP - 360

EP - 363

JO - Dalton transactions

JF - Dalton transactions

ER -

Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

Abstract

Keywords

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