Control over Rectification in Supramolecular Tunneling Junctions

Kim S. Wimbush; William F. Reus; Wilfred G. van der Wiel; David N. Reinhoudt; George M. Whitesides; Christian A. Nijhuis; Aldrik H. Velders

doi:10.1002/anie.201003286

Control over Rectification in Supramolecular Tunneling Junctions

Kim S. Wimbush, William F. Reus, Wilfred G. van der Wiel, David N. Reinhoudt, George M. Whitesides, Christian A. Nijhuis^*, Aldrik H. Velders^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

In complete control: The magnitude of current rectification in well-defined supramolecular tunneling junctions can be controlled by changing the terminal functionality (red spheres) of dendrimers (gray spheres) immobilized on a supramolecular platform (see picture). Junctions containing biferrocene and ferrocene end groups showed larger rectification ratios than junctions containing adamantyl end groups.

Original language	English
Pages (from-to)	10176-10180
Number of pages	5
Journal	Angewandte Chemie (international edition)
Volume	49
Issue number	52
DOIs	https://doi.org/10.1002/anie.201003286
Publication status	Published - 2010

Keywords

Cyclodextrins
Dendrimers
Ferrocene
Molecular electronics
Supramolecular chemistry

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10.1002/anie.201003286

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title = "Control over Rectification in Supramolecular Tunneling Junctions",

abstract = "In complete control: The magnitude of current rectification in well-defined supramolecular tunneling junctions can be controlled by changing the terminal functionality (red spheres) of dendrimers (gray spheres) immobilized on a supramolecular platform (see picture). Junctions containing biferrocene and ferrocene end groups showed larger rectification ratios than junctions containing adamantyl end groups.",

keywords = "Cyclodextrins, Dendrimers, Ferrocene, Molecular electronics, Supramolecular chemistry",

author = "Wimbush, {Kim S.} and Reus, {William F.} and {van der Wiel}, {Wilfred G.} and Reinhoudt, {David N.} and Whitesides, {George M.} and Nijhuis, {Christian A.} and Velders, {Aldrik H.}",

year = "2010",

doi = "10.1002/anie.201003286",

language = "English",

volume = "49",

pages = "10176--10180",

journal = "Angewandte Chemie (international edition)",

issn = "1433-7851",

publisher = "Wiley",

number = "52",

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TY - JOUR

T1 - Control over Rectification in Supramolecular Tunneling Junctions

AU - Wimbush, Kim S.

AU - Reus, William F.

AU - van der Wiel, Wilfred G.

AU - Reinhoudt, David N.

AU - Whitesides, George M.

AU - Nijhuis, Christian A.

AU - Velders, Aldrik H.

PY - 2010

Y1 - 2010

N2 - In complete control: The magnitude of current rectification in well-defined supramolecular tunneling junctions can be controlled by changing the terminal functionality (red spheres) of dendrimers (gray spheres) immobilized on a supramolecular platform (see picture). Junctions containing biferrocene and ferrocene end groups showed larger rectification ratios than junctions containing adamantyl end groups.

AB - In complete control: The magnitude of current rectification in well-defined supramolecular tunneling junctions can be controlled by changing the terminal functionality (red spheres) of dendrimers (gray spheres) immobilized on a supramolecular platform (see picture). Junctions containing biferrocene and ferrocene end groups showed larger rectification ratios than junctions containing adamantyl end groups.

KW - Cyclodextrins

KW - Dendrimers

KW - Ferrocene

KW - Molecular electronics

KW - Supramolecular chemistry

U2 - 10.1002/anie.201003286

DO - 10.1002/anie.201003286

M3 - Article

SN - 1433-7851

VL - 49

SP - 10176

EP - 10180

JO - Angewandte Chemie (international edition)

JF - Angewandte Chemie (international edition)

IS - 52

ER -

Control over Rectification in Supramolecular Tunneling Junctions

Abstract

Keywords

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