TY - JOUR
T1 - Controlled assembly of nanosized metallodendrimers
AU - Huck, Wilhelm T.S.
AU - van Veggel, Frank C.J.M.
AU - Reinhoudt, David N.
PY - 1996
Y1 - 1996
N2 - Up to third‐generation metallodendrimers can be constructed by a repetitive sequence of reactions with building blocks that contain two coordinatively unsaturated Pd centers (“pie” shape) and one labile, coordinating cyano group (▴, see representation below). The key steps of assembly are the displacement of the chloro ligands (▵) with AgBF4 and the in situ reaction with the cyano groups of the dendrimer building blocks to give the next generation. The resulting dendrimers have molecular masses of up to 25 kDa.
AB - Up to third‐generation metallodendrimers can be constructed by a repetitive sequence of reactions with building blocks that contain two coordinatively unsaturated Pd centers (“pie” shape) and one labile, coordinating cyano group (▴, see representation below). The key steps of assembly are the displacement of the chloro ligands (▵) with AgBF4 and the in situ reaction with the cyano groups of the dendrimer building blocks to give the next generation. The resulting dendrimers have molecular masses of up to 25 kDa.
U2 - 10.1002/anie.199612131
DO - 10.1002/anie.199612131
M3 - Article
SN - 0570-0833
VL - 35
SP - 1213
EP - 1215
JO - Angewandte Chemie, International Edition in English
JF - Angewandte Chemie, International Edition in English
IS - 11
ER -