Abstract
The application of new initiators for the ring-opening polymerization of cyclic esters has markedly improved the macromolecular engineering of biodegradable polyesters. A wide variety of complex macromolecular architectures can nowadays be prepared using these initiators. Decisive factors in achieving this are the range of monomers that can be polymerized, and the favourable rates of polymerization obtained for these monomers. The number of papers dealing with the exciting synthetic aspects of these initiators is rapidly increasing. A historic overview of the developments in this area is presented in this paper.
Original language | English |
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Title of host publication | Biorelated polymers |
Subtitle of host publication | Sustainable polymer science and technology |
Editors | Emo Chiellini, Helena Gil, Gerhart Braunegg, Johanna Buchert, Paul Gatenholm, Maarten van der Zee |
Place of Publication | Boston, MA |
Publisher | Kluwer Academic/Plenum Publishers |
Pages | 179-194 |
ISBN (Electronic) | 978-1-4757-3374-7 |
ISBN (Print) | 978-1-4419-3369-0 |
DOIs | |
Publication status | Published - 2001 |
Event | 1st International Conference on Biopolymer Technology 1999 - Coimbra, Portugal Duration: 29 Sept 1999 → 1 Oct 1999 Conference number: 1 |
Conference
Conference | 1st International Conference on Biopolymer Technology 1999 |
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Country/Territory | Portugal |
City | Coimbra |
Period | 29/09/99 → 1/10/99 |
Keywords
- Aluminium isopropoxide
- Cyclic ester
- Stannous octoate
- Aluminium alkoxide
- Macromolecular architecture