Controlling the amplification of chirality in hydrogen-bonded assemblies

Miguel Mateos timoneda, Mercedes Crego Calama, David Reinhoudt

    Research output: Contribution to journalArticleAcademicpeer-review

    22 Citations (Scopus)

    Abstract

    The amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) on hydrogen-bonded assemblies has been studied using “sergeants-and-soldiers” experiments under thermodynamically controlled conditions. Here it is shown that different substitutions and structural variations in the building blocks that form these self-assembled systems can be used to control the extent of the chiral amplification.
    Original languageUndefined
    Pages (from-to)67-79
    JournalSupramolecular chemistry
    Volume17
    Issue number1-2
    DOIs
    Publication statusPublished - 2005

    Keywords

    • Amplification of chirality
    • METIS-224849
    • Noncovalent synthesis
    • Supramolecular Chemistry
    • Hydrogen bonds
    • IR-52888

    Cite this

    Mateos timoneda, Miguel ; Crego Calama, Mercedes ; Reinhoudt, David. / Controlling the amplification of chirality in hydrogen-bonded assemblies. In: Supramolecular chemistry. 2005 ; Vol. 17, No. 1-2. pp. 67-79.
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    Controlling the amplification of chirality in hydrogen-bonded assemblies. / Mateos timoneda, Miguel; Crego Calama, Mercedes; Reinhoudt, David.

    In: Supramolecular chemistry, Vol. 17, No. 1-2, 2005, p. 67-79.

    Research output: Contribution to journalArticleAcademicpeer-review

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    AU - Mateos timoneda, Miguel

    AU - Crego Calama, Mercedes

    AU - Reinhoudt, David

    PY - 2005

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    KW - Noncovalent synthesis

    KW - Supramolecular Chemistry

    KW - Hydrogen bonds

    KW - IR-52888

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