Controlling the amplification of chirality in hydrogen-bonded assemblies

Miguel Mateos timoneda, Mercedes Crego Calama, David Reinhoudt

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    22 Citations (Scopus)

    Abstract

    The amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) on hydrogen-bonded assemblies has been studied using “sergeants-and-soldiers” experiments under thermodynamically controlled conditions. Here it is shown that different substitutions and structural variations in the building blocks that form these self-assembled systems can be used to control the extent of the chiral amplification.
    Original languageUndefined
    Pages (from-to)67-79
    JournalSupramolecular chemistry
    Volume17
    Issue number1-2
    DOIs
    Publication statusPublished - 2005

    Keywords

    • Amplification of chirality
    • METIS-224849
    • Noncovalent synthesis
    • Supramolecular Chemistry
    • Hydrogen bonds
    • IR-52888

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