Coordination networks based on boronate and benzoxaborolate ligands

Saad Sene; Marie Alix Pizzoccaro; Joris Vezzani; Marc Reinholdt; Philippe Gaveau; Dorothée Berthomieu; Sylvie Bégu; Christel Gervais; Christian Bonhomme; Guillaume Renaudin; Adel Mesbah; Arie van der Lee; Mark E. Smith; Danielle Laurencin

doi:10.3390/cryst6050048

Coordination networks based on boronate and benzoxaborolate ligands

Saad Sene, Marie Alix Pizzoccaro, Joris Vezzani, Marc Reinholdt, Philippe Gaveau, Dorothée Berthomieu, Sylvie Bégu, Christel Gervais, Christian Bonhomme, Guillaume Renaudin, Adel Mesbah, Arie van der Lee, Mark E. Smith, Danielle Laurencin^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › Academic › peer-review

9 Citations (Scopus)

Abstract

Despite the extensive range of investigations on boronic acids (R-B(OH) ₂ ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) ₃ ⁻ ), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.

Original language	English
Article number	48
Journal	Crystals
Volume	6
Issue number	5
DOIs	https://doi.org/10.3390/cryst6050048
Publication status	Published - 1 May 2016
Externally published	Yes

Keywords

Benzoxaborolate
Benzoxaborole
Boronate
Boronic acid
Coordination polymer
Crystallography
DFT
IR spectroscopy
Solid state NMR
Tri-hydroxyborate

Access to Document

10.3390/cryst6050048

Cite this

@article{ab11c0abb4b2461cb390627b7245eb72,

title = "Coordination networks based on boronate and benzoxaborolate ligands",

abstract = " Despite the extensive range of investigations on boronic acids (R-B(OH) 2 ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) 3 − ), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications. ",

keywords = "Benzoxaborolate, Benzoxaborole, Boronate, Boronic acid, Coordination polymer, Crystallography, DFT, IR spectroscopy, Solid state NMR, Tri-hydroxyborate",

author = "Saad Sene and Pizzoccaro, {Marie Alix} and Joris Vezzani and Marc Reinholdt and Philippe Gaveau and Doroth{\'e}e Berthomieu and Sylvie B{\'e}gu and Christel Gervais and Christian Bonhomme and Guillaume Renaudin and Adel Mesbah and {van der Lee}, Arie and Smith, {Mark E.} and Danielle Laurencin",

year = "2016",

month = may,

day = "1",

doi = "10.3390/cryst6050048",

language = "English",

volume = "6",

journal = "Crystals",

issn = "2073-4352",

publisher = "MDPI",

number = "5",

}

TY - JOUR

T1 - Coordination networks based on boronate and benzoxaborolate ligands

AU - Sene, Saad

AU - Pizzoccaro, Marie Alix

AU - Vezzani, Joris

AU - Reinholdt, Marc

AU - Gaveau, Philippe

AU - Berthomieu, Dorothée

AU - Bégu, Sylvie

AU - Gervais, Christel

AU - Bonhomme, Christian

AU - Renaudin, Guillaume

AU - Mesbah, Adel

AU - van der Lee, Arie

AU - Smith, Mark E.

AU - Laurencin, Danielle

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Despite the extensive range of investigations on boronic acids (R-B(OH) 2 ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) 3 − ), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.

AB - Despite the extensive range of investigations on boronic acids (R-B(OH) 2 ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) 3 − ), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.

KW - Benzoxaborolate

KW - Benzoxaborole

KW - Boronate

KW - Boronic acid

KW - Coordination polymer

KW - Crystallography

KW - DFT

KW - IR spectroscopy

KW - Solid state NMR

KW - Tri-hydroxyborate

UR - http://www.scopus.com/inward/record.url?scp=85011958904&partnerID=8YFLogxK

U2 - 10.3390/cryst6050048

DO - 10.3390/cryst6050048

M3 - Review article

AN - SCOPUS:85011958904

VL - 6

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 5

M1 - 48

ER -

Coordination networks based on boronate and benzoxaborolate ligands

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this