Coordination networks based on boronate and benzoxaborolate ligands

Saad Sene, Marie Alix Pizzoccaro, Joris Vezzani, Marc Reinholdt, Philippe Gaveau, Dorothée Berthomieu, Sylvie Bégu, Christel Gervais, Christian Bonhomme, Guillaume Renaudin, Adel Mesbah, Arie van der Lee, Mark E. Smith, Danielle Laurencin*

*Corresponding author for this work

Research output: Contribution to journalReview articleAcademicpeer-review

7 Citations (Scopus)

Abstract

Despite the extensive range of investigations on boronic acids (R-B(OH) 2 ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) 3 ), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.

Original languageEnglish
Article number48
JournalCrystals
Volume6
Issue number5
DOIs
Publication statusPublished - 1 May 2016
Externally publishedYes

Keywords

  • Benzoxaborolate
  • Benzoxaborole
  • Boronate
  • Boronic acid
  • Coordination polymer
  • Crystallography
  • DFT
  • IR spectroscopy
  • Solid state NMR
  • Tri-hydroxyborate

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