Cyanuric acid and melamine on Au(111): Structure and energetics of hydrogen-bonded networks

H. Xu; Wei Xu; Mingdong Dong; H. Gersen; Eva Rauls; M.S. Vazquez Campos; Socorro Vazquez-Campos; Mercedes Crego Calama; David Reinhoudt; Ivan Stensgaard; Erik Laegsgaard; Trolle R. Linderoth; Flemming Besenbacher

doi:10.1002/smll.200600407

Cyanuric acid and melamine on Au(111): Structure and energetics of hydrogen-bonded networks

H. Xu, Wei Xu, Mingdong Dong, H. Gersen, Eva Rauls, M.S. Vazquez Campos, Socorro Vazquez-Campos, Mercedes Crego Calama, David Reinhoudt, Ivan Stensgaard, Erik Laegsgaard, Trolle R. Linderoth, Flemming Besenbacher

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution. In addition to the expected structure with a 1:1 CA/M ratio, a novel phase with a 1:3 CA/M forms upon sequential deposition.

Original language	Undefined
Pages (from-to)	854-858
Number of pages	5
Journal	Small
Volume	3
Issue number	5
DOIs	https://doi.org/10.1002/smll.200600407
Publication status	Published - 2007

Keywords

IR-72247
Hydrogen bonding
Molecular recognition
METIS-241438
Scanning probe microscopy
Supramolecular Chemistry
Nanotechnology

Access to Document

10.1002/smll.200600407

Cite this

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title = "Cyanuric acid and melamine on Au(111): Structure and energetics of hydrogen-bonded networks",

abstract = "Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution. In addition to the expected structure with a 1:1 CA/M ratio, a novel phase with a 1:3 CA/M forms upon sequential deposition.",

keywords = "IR-72247, Hydrogen bonding, Molecular recognition, METIS-241438, Scanning probe microscopy, Supramolecular Chemistry, Nanotechnology",

author = "H. Xu and Wei Xu and Mingdong Dong and H. Gersen and Eva Rauls and {Vazquez Campos}, M.S. and Socorro Vazquez-Campos and {Crego Calama}, Mercedes and David Reinhoudt and Ivan Stensgaard and Erik Laegsgaard and Linderoth, {Trolle R.} and Flemming Besenbacher",

year = "2007",

doi = "10.1002/smll.200600407",

language = "Undefined",

volume = "3",

pages = "854--858",

journal = "Small",

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publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Cyanuric acid and melamine on Au(111): Structure and energetics of hydrogen-bonded networks

AU - Xu, H.

AU - Xu, Wei

AU - Dong, Mingdong

AU - Gersen, H.

AU - Rauls, Eva

AU - Vazquez Campos, M.S.

AU - Vazquez-Campos, Socorro

AU - Crego Calama, Mercedes

AU - Reinhoudt, David

AU - Stensgaard, Ivan

AU - Laegsgaard, Erik

AU - Linderoth, Trolle R.

AU - Besenbacher, Flemming

PY - 2007

Y1 - 2007

N2 - Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution. In addition to the expected structure with a 1:1 CA/M ratio, a novel phase with a 1:3 CA/M forms upon sequential deposition.

AB - Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution. In addition to the expected structure with a 1:1 CA/M ratio, a novel phase with a 1:3 CA/M forms upon sequential deposition.

KW - IR-72247

KW - Hydrogen bonding

KW - Molecular recognition

KW - METIS-241438

KW - Scanning probe microscopy

KW - Supramolecular Chemistry

KW - Nanotechnology

U2 - 10.1002/smll.200600407

DO - 10.1002/smll.200600407

M3 - Article

SN - 1613-6810

VL - 3

SP - 854

EP - 858

JO - Small

JF - Small

IS - 5

ER -