TY - JOUR
T1 - Cyclo dehydration reaction of polyhydrazides
T2 - I. Kinetic parameters obtained with nonisothermal thermogravimetry
AU - Gebben, B.
AU - Mulder, M.H.V.
AU - Smolders, C.A.
PY - 1988
Y1 - 1988
N2 - The thermal conversion reaction of poly-(1,3-phenyl-1,4-phenyl)-hydrazide into poly-(1,3-phenyl-1,4-phenyl)-1,3,4-oxadiazole has been studied using thermogravimetry (TG). For the evaluation of the energie of activation and other kinetic parameters of this cyclo dehydration reaction a method developed by Ozawa was used, where polymer samples are heated with different constant heating rates. With this method the energy of activation can be determined accurately as a function of the degree of conversion. In this way a parallel reaction could be observed starting at the end of the nonisothermal conversion process. The polymer was used in two different morphological states, a powder and a film. A slightly higher energy of activation and a considerably higher pre-exponential factor were observed for the film indicating a dependency of the kinetics on the morphological state or on the history of the polymer sample.
AB - The thermal conversion reaction of poly-(1,3-phenyl-1,4-phenyl)-hydrazide into poly-(1,3-phenyl-1,4-phenyl)-1,3,4-oxadiazole has been studied using thermogravimetry (TG). For the evaluation of the energie of activation and other kinetic parameters of this cyclo dehydration reaction a method developed by Ozawa was used, where polymer samples are heated with different constant heating rates. With this method the energy of activation can be determined accurately as a function of the degree of conversion. In this way a parallel reaction could be observed starting at the end of the nonisothermal conversion process. The polymer was used in two different morphological states, a powder and a film. A slightly higher energy of activation and a considerably higher pre-exponential factor were observed for the film indicating a dependency of the kinetics on the morphological state or on the history of the polymer sample.
U2 - 10.1002/pola.1988.080260706
DO - 10.1002/pola.1988.080260706
M3 - Article
SN - 0887-624X
VL - 26
SP - 1743
EP - 1755
JO - Journal of polymer science. Part A: Polymer chemistry
JF - Journal of polymer science. Part A: Polymer chemistry
IS - 7
ER -