Deep eutectic solvent pretreatment and subsequent saccharification of corncob

Alessandra Procentese, Erin Johnson, Valerie Orr, Anna Garruto Campanile, Jeffery A. Wood, Antonio Marzocchella, Lars Rehmann

Research output: Contribution to journalArticleAcademicpeer-review

151 Citations (Scopus)

Abstract

Ionic liquid (ILs) pretreatment of lignocellulosic biomass has attracted broad scientific interest, despite high costs, possible toxicity and energy intensive recycling. An alternative group of ionic solvents with similar physicochemical properties are deep eutectic solvents (DESs). Corncob residues were pretreated with three different DES systems: choline chloride and glycerol, choline chloride and imidazole, choline chloride and urea. The pretreated biomass was characterised in terms of lignin content, sugars concentration, enzymatic digestibility and crystallinity index. A reduction of lignin and hemicellulose content resulted in increased crystallinity of the pretreated biomass while the crystallinity of the cellulose fraction could be reduced, depending on DES system and operating conditions. The subsequent enzymatic saccharification was enhanced in terms of rate and extent. A total of 41. g fermentable sugars (27. g glucose and 14. g xylose) could be recovered from 100. g corncob, representing 76% (86% and 63%) of the initially available carbohydrates.
Original languageEnglish
Pages (from-to)31-36
Number of pages6
JournalBioresource technology
Volume192
DOIs
Publication statusPublished - 1 Sep 2015

Keywords

  • Deep eutectic solvents
  • Enzymatic hydrolysis
  • Ionic liquids
  • Lignocellulosic biomass

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