TY - JOUR
T1 - Design of phosphonated imidazolium-based ionic liquids grafted on γ-alumina
T2 - Potential model for hybrid membranes
AU - Pizzoccaro, Marie Alix
AU - Drobek, Martin
AU - Petit, Eddy
AU - Guerrero, Gilles
AU - Hesemann, Peter
AU - Julbe, Anne
PY - 2016/8/1
Y1 - 2016/8/1
N2 -
Imidazolium bromide-based ionic liquids bearing phosphonyl groups on the cationic part were synthesized and grafted on γ-alumina (γ-Al
2
O
3
) powders. These powders were prepared as companion samples of conventional mesoporous γ-alumina membranes, in order to favor a possible transfer of the results to supported membrane materials, which could be used for CO
2
separation applications. Effective grafting was demonstrated using energy dispersive X-ray spectrometry (EDX), N
2
adsorption measurements, fourier transform infrared spectroscopy (FTIR), and special attention was paid to
31
P and
13
C solid state nuclear magnetic resonance spectroscopy (NMR).
AB -
Imidazolium bromide-based ionic liquids bearing phosphonyl groups on the cationic part were synthesized and grafted on γ-alumina (γ-Al
2
O
3
) powders. These powders were prepared as companion samples of conventional mesoporous γ-alumina membranes, in order to favor a possible transfer of the results to supported membrane materials, which could be used for CO
2
separation applications. Effective grafting was demonstrated using energy dispersive X-ray spectrometry (EDX), N
2
adsorption measurements, fourier transform infrared spectroscopy (FTIR), and special attention was paid to
31
P and
13
C solid state nuclear magnetic resonance spectroscopy (NMR).
KW - Grafting
KW - Hybrid membrane
KW - Imidazolium-based ionic liquids
KW - Phosphonate coupling agent
KW - Solid state NMR
KW - γ-alumina
UR - http://www.scopus.com/inward/record.url?scp=85016260716&partnerID=8YFLogxK
U2 - 10.3390/ijms17081212
DO - 10.3390/ijms17081212
M3 - Article
C2 - 27472321
AN - SCOPUS:85016260716
SN - 1661-6596
VL - 17
JO - International journal of molecular sciences
JF - International journal of molecular sciences
IS - 8
M1 - 1212
ER -
