Designer multi-functional comb-polymers for surface engineering of quantum dots on the nanoscale

Dominik Jańczewski; Nikodem Tomczak; Yin Win Khin; Ming-Yong Han; G. Julius Vancso

doi:10.1016/j.eurpolymj.2008.08.047

Designer multi-functional comb-polymers for surface engineering of quantum dots on the nanoscale

Dominik Jańczewski, Nikodem Tomczak, Yin Win Khin, Ming-Yong Han, G. Julius Vancso

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Abstract

Synthesis, characterization and cell-biomarker applications for a novel series of comb-copolymers featuring hydrophobic amide side groups, carboxylates and other functionalities such as polymerizable side chains and PEG oligomers are reported. When used as polymer ligand shell for trioctylphosphine oxide (TOPO) coated quantum dots (QDs) these copolymers effectively solubilise CdSe/ZnS QDs in water. A systematic study was carried out to find the relation between the molecular structure of the copolymers, their ability to coat the QDs, and to suspend the nanocrystals in water. To demonstrate potential applications, highly luminescent QD/polymer assemblies were internalized into living and fixed cells.

Original language	English
Pages (from-to)	3-9
Number of pages	7
Journal	European polymer journal
Volume	45
Issue number	1
DOIs	https://doi.org/10.1016/j.eurpolymj.2008.08.047
Publication status	Published - 2009
Externally published	Yes

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22/4 OA procedure

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10.1016/j.eurpolymj.2008.08.047

Janczewski2009designerFinal published version, 380 KBLicence: Taverne

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title = "Designer multi-functional comb-polymers for surface engineering of quantum dots on the nanoscale",

abstract = "Synthesis, characterization and cell-biomarker applications for a novel series of comb-copolymers featuring hydrophobic amide side groups, carboxylates and other functionalities such as polymerizable side chains and PEG oligomers are reported. When used as polymer ligand shell for trioctylphosphine oxide (TOPO) coated quantum dots (QDs) these copolymers effectively solubilise CdSe/ZnS QDs in water. A systematic study was carried out to find the relation between the molecular structure of the copolymers, their ability to coat the QDs, and to suspend the nanocrystals in water. To demonstrate potential applications, highly luminescent QD/polymer assemblies were internalized into living and fixed cells.",

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AU - Jańczewski, Dominik

AU - Tomczak, Nikodem

AU - Khin, Yin Win

AU - Han, Ming-Yong

AU - Vancso, G. Julius

PY - 2009

Y1 - 2009

N2 - Synthesis, characterization and cell-biomarker applications for a novel series of comb-copolymers featuring hydrophobic amide side groups, carboxylates and other functionalities such as polymerizable side chains and PEG oligomers are reported. When used as polymer ligand shell for trioctylphosphine oxide (TOPO) coated quantum dots (QDs) these copolymers effectively solubilise CdSe/ZnS QDs in water. A systematic study was carried out to find the relation between the molecular structure of the copolymers, their ability to coat the QDs, and to suspend the nanocrystals in water. To demonstrate potential applications, highly luminescent QD/polymer assemblies were internalized into living and fixed cells.

AB - Synthesis, characterization and cell-biomarker applications for a novel series of comb-copolymers featuring hydrophobic amide side groups, carboxylates and other functionalities such as polymerizable side chains and PEG oligomers are reported. When used as polymer ligand shell for trioctylphosphine oxide (TOPO) coated quantum dots (QDs) these copolymers effectively solubilise CdSe/ZnS QDs in water. A systematic study was carried out to find the relation between the molecular structure of the copolymers, their ability to coat the QDs, and to suspend the nanocrystals in water. To demonstrate potential applications, highly luminescent QD/polymer assemblies were internalized into living and fixed cells.

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DO - 10.1016/j.eurpolymj.2008.08.047

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EP - 9

JO - European polymer journal

JF - European polymer journal

IS - 1

ER -

Designer multi-functional comb-polymers for surface engineering of quantum dots on the nanoscale

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Keywords

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