Determination of Hyperpolarizability Tensor Components by Depolarized Hyper Rayleigh Scattering

G.J.T. Heesink; A.G.T. Ruiter; N.F. van Hulst; B. Bölger

doi:10.1103/PhysRevLett.71.999

Determination of Hyperpolarizability Tensor Components by Depolarized Hyper Rayleigh Scattering

G.J.T. Heesink, A.G.T. Ruiter, N.F. van Hulst, B. Bölger

Optical Sciences

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Abstract

Depolarized hyper Rayleigh scattering of para-nitroaniline (C2v symmetry) and nitrocalix[4]arene (C4v symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.

Original language	English
Pages (from-to)	999-1002
Number of pages	4
Journal	Physical review letters
Volume	71
Issue number	7
DOIs	https://doi.org/10.1103/PhysRevLett.71.999
Publication status	Published - 1993

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title = "Determination of Hyperpolarizability Tensor Components by Depolarized Hyper Rayleigh Scattering",

abstract = "Depolarized hyper Rayleigh scattering of para-nitroaniline (C2v symmetry) and nitrocalix[4]arene (C4v symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.",

author = "G.J.T. Heesink and A.G.T. Ruiter and {van Hulst}, N.F. and B. B{\"o}lger",

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AU - Heesink, G.J.T.

AU - Ruiter, A.G.T.

AU - van Hulst, N.F.

AU - Bölger, B.

PY - 1993

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N2 - Depolarized hyper Rayleigh scattering of para-nitroaniline (C2v symmetry) and nitrocalix[4]arene (C4v symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.

AB - Depolarized hyper Rayleigh scattering of para-nitroaniline (C2v symmetry) and nitrocalix[4]arene (C4v symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.

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DO - 10.1103/PhysRevLett.71.999

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JO - Physical review letters

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Determination of Hyperpolarizability Tensor Components by Depolarized Hyper Rayleigh Scattering

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