Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6

Adriaan J.H. Bunk, Hans G. Regtuit, J.W.A. van den Berg, R.J. Gaymans, Jan Schuyer

Research output: Contribution to journalArticleAcademic

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Abstract

In this report the results are summarized of measurements concerning the influence of intermolecular hydrogen bridge formation on the mechanisms responsible for the so-called p- and y-relaxations in the dielectric loss spectrum of nylon 6.6’) (see McCrum et al.’, p. 478497). To that end the loss spectra and the IR carbonyl absorptions in the range from 1 500 to 1 700 cm - were studied of polyester 6.6**)a nd of nylon 6.6, modified by partly substitution of amide-hydrogen by methyl or ethyl groups. This work is intended to give a contribution to the elucidation of the still existing controversy2- s, concerning the mechanisms mentioned above. Up till now, the idea of Woodward et aL6) of N-substitution as a tool in the interpretation of these secondary transitions in the dielectric loss spectrum of nylon 6.6, was not pursued further.
Original languageUndefined
Pages (from-to)3511-3515
JournalMakromolekulare Chemie
Volume176
Issue number11
DOIs
Publication statusPublished - 1975

Keywords

  • IR-70770

Cite this

Bunk, A. J. H., Regtuit, H. G., van den Berg, J. W. A., Gaymans, R. J., & Schuyer, J. (1975). Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6. Makromolekulare Chemie, 176(11), 3511-3515. https://doi.org/10.1002/macp.1975.021761134
Bunk, Adriaan J.H. ; Regtuit, Hans G. ; van den Berg, J.W.A. ; Gaymans, R.J. ; Schuyer, Jan. / Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6. In: Makromolekulare Chemie. 1975 ; Vol. 176, No. 11. pp. 3511-3515.
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abstract = "In this report the results are summarized of measurements concerning the influence of intermolecular hydrogen bridge formation on the mechanisms responsible for the so-called p- and y-relaxations in the dielectric loss spectrum of nylon 6.6’) (see McCrum et al.’, p. 478497). To that end the loss spectra and the IR carbonyl absorptions in the range from 1 500 to 1 700 cm - were studied of polyester 6.6**)a nd of nylon 6.6, modified by partly substitution of amide-hydrogen by methyl or ethyl groups. This work is intended to give a contribution to the elucidation of the still existing controversy2- s, concerning the mechanisms mentioned above. Up till now, the idea of Woodward et aL6) of N-substitution as a tool in the interpretation of these secondary transitions in the dielectric loss spectrum of nylon 6.6, was not pursued further.",
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Bunk, AJH, Regtuit, HG, van den Berg, JWA, Gaymans, RJ & Schuyer, J 1975, 'Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6' Makromolekulare Chemie, vol. 176, no. 11, pp. 3511-3515. https://doi.org/10.1002/macp.1975.021761134

Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6. / Bunk, Adriaan J.H.; Regtuit, Hans G.; van den Berg, J.W.A.; Gaymans, R.J.; Schuyer, Jan.

In: Makromolekulare Chemie, Vol. 176, No. 11, 1975, p. 3511-3515.

Research output: Contribution to journalArticleAcademic

TY - JOUR

T1 - Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6

AU - Bunk, Adriaan J.H.

AU - Regtuit, Hans G.

AU - van den Berg, J.W.A.

AU - Gaymans, R.J.

AU - Schuyer, Jan

PY - 1975

Y1 - 1975

N2 - In this report the results are summarized of measurements concerning the influence of intermolecular hydrogen bridge formation on the mechanisms responsible for the so-called p- and y-relaxations in the dielectric loss spectrum of nylon 6.6’) (see McCrum et al.’, p. 478497). To that end the loss spectra and the IR carbonyl absorptions in the range from 1 500 to 1 700 cm - were studied of polyester 6.6**)a nd of nylon 6.6, modified by partly substitution of amide-hydrogen by methyl or ethyl groups. This work is intended to give a contribution to the elucidation of the still existing controversy2- s, concerning the mechanisms mentioned above. Up till now, the idea of Woodward et aL6) of N-substitution as a tool in the interpretation of these secondary transitions in the dielectric loss spectrum of nylon 6.6, was not pursued further.

AB - In this report the results are summarized of measurements concerning the influence of intermolecular hydrogen bridge formation on the mechanisms responsible for the so-called p- and y-relaxations in the dielectric loss spectrum of nylon 6.6’) (see McCrum et al.’, p. 478497). To that end the loss spectra and the IR carbonyl absorptions in the range from 1 500 to 1 700 cm - were studied of polyester 6.6**)a nd of nylon 6.6, modified by partly substitution of amide-hydrogen by methyl or ethyl groups. This work is intended to give a contribution to the elucidation of the still existing controversy2- s, concerning the mechanisms mentioned above. Up till now, the idea of Woodward et aL6) of N-substitution as a tool in the interpretation of these secondary transitions in the dielectric loss spectrum of nylon 6.6, was not pursued further.

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DO - 10.1002/macp.1975.021761134

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JF - Macromolecular chemistry and physics

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Bunk AJH, Regtuit HG, van den Berg JWA, Gaymans RJ, Schuyer J. Dielectric loss of N-substituted nylon 6.6 and of polyester 6.6. Makromolekulare Chemie. 1975;176(11):3511-3515. https://doi.org/10.1002/macp.1975.021761134