Diffusivity measurements in some organic solvents by a gas-liquid diaphragm cell

R.J. Littel; R.J. Littel; Geert Versteeg; Willibrordus Petrus Maria van Swaaij

doi:10.1021/je00005a014

Diffusivity measurements in some organic solvents by a gas-liquid diaphragm cell

R.J. Littel, R.J. Littel, Geert Versteeg, Willibrordus Petrus Maria van Swaaij

Faculty of Science and Technology

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A diaphragm cell has been developed for the measurement of diffusion coefficients of gases In liquids. The diaphragm cell is operated batchwise with respect to both gas and liquid phases, and the diffusion process Is followed by means of the gas pressure decrease which is recorded by means of a pressure transducer. The diaphragm cell has been calibrated with some well-known gas-liquid systems. The present diaphragm cell was shown to be very suitable for the determination of diffusion coefficients at higher temperatures. The diffusion coefficient of C02 and propene In toluene has been measured at temperatures ranging from 298 to 328 K. The dmusivity for various other gas-liquid systems has been determined at 298 K.

Original language	English
Pages (from-to)	42-45
Number of pages	4
Journal	Journal of chemical & engineering data
Volume	37
Issue number	1
DOIs	https://doi.org/10.1021/je00005a014
Publication status	Published - 1992

Keywords

METIS-106054
IR-82880

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10.1021/je00005a014

Littel92diffusivity

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title = "Diffusivity measurements in some organic solvents by a gas-liquid diaphragm cell",

abstract = "A diaphragm cell has been developed for the measurement of diffusion coefficients of gases In liquids. The diaphragm cell is operated batchwise with respect to both gas and liquid phases, and the diffusion process Is followed by means of the gas pressure decrease which is recorded by means of a pressure transducer. The diaphragm cell has been calibrated with some well-known gas-liquid systems. The present diaphragm cell was shown to be very suitable for the determination of diffusion coefficients at higher temperatures. The diffusion coefficient of C02 and propene In toluene has been measured at temperatures ranging from 298 to 328 K. The dmusivity for various other gas-liquid systems has been determined at 298 K.",

keywords = "METIS-106054, IR-82880",

author = "R.J. Littel and R.J. Littel and Geert Versteeg and {van Swaaij}, {Willibrordus Petrus Maria}",

year = "1992",

doi = "10.1021/je00005a014",

language = "English",

volume = "37",

pages = "42--45",

journal = "Journal of chemical & engineering data",

issn = "0021-9568",

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T1 - Diffusivity measurements in some organic solvents by a gas-liquid diaphragm cell

AU - Littel, R.J.

AU - Versteeg, Geert

AU - van Swaaij, Willibrordus Petrus Maria

PY - 1992

Y1 - 1992

N2 - A diaphragm cell has been developed for the measurement of diffusion coefficients of gases In liquids. The diaphragm cell is operated batchwise with respect to both gas and liquid phases, and the diffusion process Is followed by means of the gas pressure decrease which is recorded by means of a pressure transducer. The diaphragm cell has been calibrated with some well-known gas-liquid systems. The present diaphragm cell was shown to be very suitable for the determination of diffusion coefficients at higher temperatures. The diffusion coefficient of C02 and propene In toluene has been measured at temperatures ranging from 298 to 328 K. The dmusivity for various other gas-liquid systems has been determined at 298 K.

AB - A diaphragm cell has been developed for the measurement of diffusion coefficients of gases In liquids. The diaphragm cell is operated batchwise with respect to both gas and liquid phases, and the diffusion process Is followed by means of the gas pressure decrease which is recorded by means of a pressure transducer. The diaphragm cell has been calibrated with some well-known gas-liquid systems. The present diaphragm cell was shown to be very suitable for the determination of diffusion coefficients at higher temperatures. The diffusion coefficient of C02 and propene In toluene has been measured at temperatures ranging from 298 to 328 K. The dmusivity for various other gas-liquid systems has been determined at 298 K.

KW - METIS-106054

KW - IR-82880

U2 - 10.1021/je00005a014

DO - 10.1021/je00005a014

M3 - Article

SN - 0021-9568

VL - 37

SP - 42

EP - 45

JO - Journal of chemical & engineering data

JF - Journal of chemical & engineering data

IS - 1

ER -

Diffusivity measurements in some organic solvents by a gas-liquid diaphragm cell

Abstract

Keywords

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