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Dinuclear, diuranyl-containing metallomacrocycles: neutral receptors for dicarboxylates

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Abstract

Dinuclear UO2-sal(oph)en metallomacrocycles 1 and 2, containing flexible and rigid cavities, respectively, have been found linearly to recognise and form strong solution complexes with terephthalate, succinate and fumarate dianions in (CD3)2SO; weaker interactions between these hosts and the shorter malonate and monoanionic benzoate were observed.
Original languageEnglish
Pages (from-to)135-139
Number of pages5
JournalJournal of the Chemical Society. Perkin transactions II
Volume1995
Issue number1
DOIs
Publication statusPublished - 1995

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