Directional movement of dendritic marcomolecules on gradient surfaces

Theresa Chang, Dorota I. Rozkiewicz, Bart Jan Ravoo, E.W. Meijer*, David N. Reinhoudt

*Corresponding author for this work

    Research output: Contribution to journalArticleAcademicpeer-review

    44 Citations (Scopus)
    1 Downloads (Pure)

    Abstract

    A gradient-driven methodology has been developed to manipulate the movement of dendritic macromolecules. Poly(propyleneimine) dendrimers, labeled with rhodamine B, are attached to glass substrates via multiple imine bonds. The dendrimers are able to move on the surface by the hydrolysis and re-formation of these imine bonds. In the absence of an external stimulus, this random movement results in a two-dimensional diffusion on the substrate. We are able to bias the movement of these nanoparticles by means of an aldehyde gradient on the glass substrate.
    Original languageEnglish
    Pages (from-to)978-980
    Number of pages3
    JournalNano letters
    Volume7
    Issue number4
    DOIs
    Publication statusPublished - 2007

    Keywords

    • n/a OA procedure

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